Synthesis and single-crystal structure analysis of [Ba(NH3)7]C60•NH3

被引：26

作者：

Himmel, K ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Rheinische Friedrich Wilhelms Universitat Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 13期

关键词：

D O I：

10.1021/ic9715512

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound demonstrates that static Jahn-Teller distortion in C-60(2-) is negligible. Weak interactions between the ammonia ligands and the fullerenes lead to localized C-60(2-) anions without any hint of orientational disorder. [Ba(NH3)(7)]C-60. NH3 is prepared from stoichiometric amounts of barium and C-60 in liquid ammonia. It is composed from monocapped trigonal antiprismatic [Ba(NH3)(7)](2+) ammine complexes and ordered C-60(2-) anions, forming a distorted rock salt type structure.

引用

页码：3437 / +

页数：4

共 33 条

[1] JAHN-TELLER DISTORTIONS IN SOLID C-20 AND OTHER FULLERENE STRUCTURES [J].

ADAMS, GB ;

SANKEY, OF ;

PAGE, JB ;

OKEEFFE, M .

CHEMICAL PHYSICS, 1993, 176 (01) :61-66

[2] LEAST-SQUARES ABSOLUTE-STRUCTURE REFINEMENT - PRACTICAL EXPERIENCE AND ANCILLARY CALCULATIONS [J].

BERNARDINELLI, G ;

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1985, 41 (SEP) :500-511

[3] SYNTHESIS AND ELECTRONIC CHARACTERIZATION OF DISCRETE BUCKMINSTERFULLERIDE SALTS - C-60(2-) AND C-60(3-) [J].

BHYRAPPA, P ;

PAUL, P ;

STINCHCOMBE, J ;

BOYD, PDW ;

REED, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (23) :11004-11005

[4] ELECTROCRYSTALLIZATION AND CRYSTAL-STRUCTURE DETERMINATION OF PH(4)PC(60)CENTER-DOT-PH(4)PCL [J].

BILOW, U ;

JANSEN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :403-404

[5] THE C-60(2-) FULLERIDE ION [J].

BOYD, PDW ;

BHYRAPPA, P ;

PAUL, P ;

STINCHCOMBE, J ;

BOLSKAR, RD ;

SUN, YP ;

REED, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) :2907-2914

[6] THE STRUCTURE OF C-60 - ORIENTATIONAL DISORDER IN THE LOW-TEMPERATURE MODIFICATION OF C-60 [J].

BURGI, HB ;

BLANC, E ;

SCHWARZENBACH, D ;

LIU, SZ ;

LU, YJ ;

KAPPES, MM ;

IBERS, JA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (05) :640-643

[7]

Carroll K. Johnson, 1965, ORTEP FORTRAN THERMA

[8] COMMENTS ON THE CARBON CLUSTER C-60 AND ON ITS COMPLEXES WITH ALKALINE ELEMENTS [J].

CORONGIU, G ;

CLEMENTI, E .

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1992, 42 (05) :1185-1208

[9] CRYSTAL-STRUCTURE AND BONDING OF ORDERED C60 [J].

DAVID, WIF ;

IBBERSON, RM ;

MATTHEWMAN, JC ;

PRASSIDES, K ;

DENNIS, TJS ;

HARE, JP ;

KROTO, HW ;

TAYLOR, R ;

WALTON, DRM .

NATURE, 1991, 353 (6340) :147-149

[10] ELECTRONIC-STRUCTURE OF NEUTRAL AND CHARGED C-60 CLUSTERS [J].

DECOULON, V ;

MARTINS, JL ;

REUSE, F .

PHYSICAL REVIEW B, 1992, 45 (23) :13671-13676

← 1 2 3 4 →