Effect of ligands on the thermolysis of the double complexes [Co(NH3)6]2C2O4[Cu(C2O4)2]2 and [Co(NH3)6]Cl[Cu(C7H4O3)2]

被引：7
作者：
Domonov, D. P. [1 ]
Pechenyuk, S. I. [1 ]
Mikhailova, N. L. [1 ]
Belyaevskii, T. [1 ]
机构：
[1] Russian Acad Sci, Kola Res Ctr, Tananaev Inst Rare Element & Mineral Chem & Techn, Apatity 184200, Murmansk Oblast, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 07期
关键词：
Complexation;
D O I：
10.1134/S0036023607070091
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The thermolysis of the complexes [Co(NH3)(6)](2)C2O4[Cu(C2O4)(2)](2) (I) and [Co(NH3)(6)]Cl[Cu(C7H4O3)(2)] (II) in air and hydrogen at 200, 350, and 500 degrees C and the composition and properties of the thermolysis products are considered. The oxidative thermolysis of the complexes yields mixtures of cobalt and copper oxides, including mixed ones. The reductive thermolysis of the complexes yields a Co+Cu bimetallic powder in the case of compound I and a Co+Cu+C powder in the case of compound II. The thermal behavior of the complexes is governed by the nature of the ligand coordinated to the copper atom. The observed data are explicable in terms of the properties of this ligand. The chemistry of the oxidative and reductive thermolysis is discussed.
引用
收藏
页码：1027 / 1032
页数：6
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