A short review of cathode poisoning and corrosion in solid oxide fuel cell

被引：158
作者：
Yang, Zhibin [1 ,3 ]
Guo, Mengyuan [1 ]
Wang, Ning [1 ]
Ma, Chaoyang [1 ]
Wang, Jingle [1 ]
Han, Minfang [2 ,3 ]
机构：
[1] China Univ Min & Technol, Union Res Ctr Fuel Cell, Sch Chem & Environm Engn, Beijing 100083, Peoples R China
[2] Tsinghua Univ, Dept Thermal Engn, State Key Lab Power Syst, Beijing 100084, Peoples R China
[3] Tsinghua Innovat Ctr Dongguan, Dongguan 523808, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2017年 / 42卷 / 39期
基金：
国家重点研发计划;
关键词：
Solid oxide fuel cell; Cathode; Corrosion; Poisoning; CHROMIUM-CONTAINING ALLOY; SOFC CATHODE; IT-SOFC; BA0.9CO0.7FE0.2NB0.1O3-DELTA CATHODE; EXCHANGE KINETICS; OXYGEN PERMEATION; COMPOSITE CATHODE; SURFACE EXCHANGE; CARBON-DIOXIDE; PERFORMANCE;
D O I：
10.1016/j.ijhydene.2017.08.057
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Solid oxide fuel cell (SOFC) has been recognized as a promising energy conversion device that is expected to play a critical role in solving the global energy and environmental challenges, however, the durability of SOFC under practical working conditions has limited its wide spread deployment and commercialization. Specifically, SOFC cathode often suffers from various contaminations such as Cr and Si arising from the interconnect and sealing materials, respectively, as well as humidity and CO2 which are inherent in ambient air, resulting in serious issues in long-term performance degradation. In this review, the impacts of certain poisoning and corrosions on SOFC cathode are introduced, and the latest results of durability research on the corrosion resistant properties of cathode under CO2, humidity, Cr and Si-containing conditions are reviewed. The poisoning and corrosion mechanism and durability of these aspects are systematically assessed and discussed. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：24948 / 24959
页数：12
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