Photoluminescence, photo-stimulated luminescence and thermoluminescence properties of CaB2O4 crystals activated with Ce3+

被引:13
作者
Fujimoto, Yutaka [1 ]
Yanagida, Takayuki [2 ]
Koshimizu, Masanori [1 ]
Asai, Keisuke [1 ]
机构
[1] Tohoku Univ, Aoba Ku, Sendai, Miyagi 9808579, Japan
[2] Kyushu Inst Technol, Wakamatsu Ku, Kitakyushu, Fukuoka 8080196, Japan
关键词
Photo-stimulated luminescence; Thermoluminescence; Ce3+ 5d-4f transition; METABORATE;
D O I
10.1016/j.optmat.2014.11.049
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Photoluminescence (PL), photo-stimulated luminescence (PSL), and thermoluminescence (TL) properties of a Ce-doped CaB2O4 crystal were studied. The Ce-doped crystal was prepared by the simple solidification method using a Pt crucible under nitrogen atmosphere. A PL emission band in the 350-370 nm wavelength range was obtained under excitation at 325 nm owing to the 5d (t(2g))-4f (F-2(5/2), F-2(7/2))-allowed transition of the Ce3+ emission center. The fluorescence quantum efficiency and the decay time of Ce3+ were estimated to be about 70% and 29 ns, respectively. The 5d-4f emission band of Ce3+ also appeared in the 350-370 nm wavelength range in the TL. and PSL spectra. Good linear TL and PSL responses were observed in the 1-1000 mGy and 1-10,000 mGy X-ray dose range, respectively. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:49 / 52
页数:4
相关论文
共 25 条
  • [1] IMAGING PLATE ILLUMINATES MANY FIELDS
    AMEMIYA, Y
    MIYAHARA, J
    [J]. NATURE, 1988, 336 (6194) : 89 - 90
  • [2] Luminescence and thermoluminescence of alkaline earth metaborates
    Berezovskaya, I. V.
    Efryushina, N. P.
    Voloshinovskii, A. S.
    Stryganyuk, G. B.
    Pir, P. V.
    Dotsenko, V. P.
    [J]. RADIATION MEASUREMENTS, 2007, 42 (4-5) : 878 - 881
  • [3] The 4fn⇆4fn-15d transitions of the trivalent lanthanides in halogenides and chalcogenides
    Dorenbos, P
    [J]. JOURNAL OF LUMINESCENCE, 2000, 91 (1-2) : 91 - 106
  • [4] DRISCOLL CMH, 1986, RADIAT PROT DOSIM, V17, P367
  • [5] Optical and scintillation properties of Pr3+-doped Ca3(BO3)2 single crystals
    Fujimoto, Y.
    Yanagida, T.
    Yokota, Y.
    Kawaguchi, N.
    Fukuda, K.
    Totsuka, D.
    Watanabe, K.
    Yamazaki, A.
    Chani, V.
    Yoshikawa, A.
    [J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2011, 248 (02): : 444 - 447
  • [6] Characterizations of Ce3+-Doped CaB2O4 Crystalline Scintillator
    Fujimoto, Yutaka
    Yanagida, Takayuki
    Kawaguchi, Noriaki
    Kurosawa, Shunsuke
    Fukuda, Kentaro
    Totsuka, Daisuke
    Watanabe, Kenichi
    Yamazaki, Atsushi
    Yokota, Yuui
    Yoshikawa, Akira
    [J]. CRYSTAL GROWTH & DESIGN, 2012, 12 (01) : 142 - 146
  • [7] Growth and characterization of Ce-doped Ca3(BO3)2 crystals for neutron scintillator
    Fujimoto, Yutaka
    Yanagida, Takayuki
    Tanaka, Hidehiko
    Yokota, Yuui
    Kawaguti, Noriaki
    Fukuda, Kentaro
    Totsuka, Daisuke
    Watanabe, Kenichi
    Yamazaki, Atsushi
    Yoshikawa, Akira
    [J]. JOURNAL OF CRYSTAL GROWTH, 2011, 318 (01) : 784 - 787
  • [8] Dosimetric characterisation of a new production of MgB4O7:Dy,Na thermoluminescent material
    Furetta, C
    Prokic, M
    Salamon, R
    Kitis, G
    [J]. APPLIED RADIATION AND ISOTOPES, 2000, 52 (02) : 243 - 250
  • [9] Thermoluminescence characteristics of copper activated calcium borate nanocrystals (CaB4O7:Cu)
    Haghiri, Maryam Erfani
    Saion, Elias
    Soltani, Nayereh
    Abdullah, Wan Saffiey Wan
    Navasery, Manizheh
    Hashim, Mansor
    [J]. JOURNAL OF LUMINESCENCE, 2013, 141 : 177 - 183
  • [10] Strontium metaborate, SrB2O4
    Kim, JB
    Lee, KS
    Suh, IH
    Lee, JH
    Park, JR
    Shin, YH
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 498 - 500