Solubilization and Thermodynamic Attributes of Nickel Phenanthroline Complex in Micellar Media of Sodium 2-Ethyl Hexyl Sulfate and Sodium Bis(2-ethyl hexyl) Sulfosuccinate

被引：12

作者：

Noor, Sadia ^{[2
,3
]}

Rashid, Muhammad Abid ^{[1
,4
,5
]}

机构：

[1] Univ Agr Faisalabad, Dept Chem, Faisalabad, Pakistan

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[3] Univ Burgos, Area Quim Organ, Dept Quim, Burgos, Spain

[4] Univ Karachi, HEJ Res Inst Chem, Karachi, Pakistan

[5] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Munster, Germany

来源：

TENSIDE SURFACTANTS DETERGENTS | 2019年 / 56卷 / 06期

关键词：

Nickel complex; anionic surfactants; solubilization; electrical conductivity; UV-Vis spectroscopy; SHORT HYDROGEN-BONDS; DODECYL-SULFATE; BIOLOGICAL-PROPERTIES; ANIONIC SURFACTANTS; CRYSTAL-STRUCTURE; AMMONIUM BROMIDE; WATER; 1,10-PHENANTHROLINE; COBALT(II); MICELLIZATION;

D O I：

10.3139/113.110653

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Micellar solubilization and physicochemical behaviour of [Ni(phen)(3)]F-2 EtOH center dot MeOH center dot 8 H2O complex in sodium 2-ethylhexyl sulfate and sodium bis(2-ethyl hexyl) sulfosuccinate is addressed in this paper. The interactions of surfactants in the solution of nickel complex were studied by UV-Vis spectroscopy and electrical conductivity. The extent of solubilization in terms of partitioning and binding parameters was determined by UV-Vis spectroscopy, whereas conductivity data were employed to calculate critical micellar concentration and other thermodynamic parameters of micellization. The value of critical micellar concentration increased in both surfactants due to structure breaking effect of nickel complex. The complex showed significant antioxidant radical scavenging and hemolytic activities, without any substantial cytotoxic activity against 3T3 cell line.

引用

页码：490 / 498

页数：9

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