Multifunctional Metal-Organic Frameworks for Photocatalysis

被引：566

作者：

Wang, Sibo ^{[1
]}

Wang, Xinchen ^{[1
]}

机构：

[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

来源：

SMALL | 2015年 / 11卷 / 26期

基金：

中国国家自然科学基金;

关键词：

metal-organic frameworks; MOFs; photocatalysis; photosynthesis; water splitting; CO2; reduction; organic transformation; PHOTOCHEMICAL HYDROGEN-PRODUCTION; VISIBLE-LIGHT; CO2; REDUCTION; CARBON-DIOXIDE; WATER OXIDATION; ARTIFICIAL PHOTOSYNTHESIS; HETEROGENEOUS PHOTOCATALYSTS; SELECTIVE OXIDATION; FORMIC-ACID; SEMICONDUCTOR;

D O I：

10.1002/smll.201500084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) have attracted significant research attention in diverse areas due to their unique physical and chemical characteristics that allow their innovative application in various research fields. Recently, the application of MOFs in heterogeneous photocatalysis for water splitting, CO2 reduction, and organic transformation have emerged, aiming at providing alternative solutions to address the world-wide energy and environmental problems by taking advantage of the unique porous structure together with ample physicochemical properties of the metal centers and organic ligands in MOFs. In this review, the latest progress in MOF-involved solar-to-chemical energy conversion reactions are summarized according to their different roles in the photoredox chemical systems, e.g., photocatalysts, co-catalysts, and hosts. The achieved progress and existing problems are evaluated and proposed, and the opportunities and challenges of MOFs and their related materials for their advanced development in photocatalysis are discussed and anticipated.

引用

页码：3097 / 3112

页数：16

共 124 条

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