Synthesis and Crystal Structures of Sm(III) Complex Assembled from Pyridine-Carboxylate

被引：0
|
作者：
Zhou, Lianwen
机构：
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 03期
关键词：
Coordination polymer; Hydrothermal synthesis; Crystal structure; COORDINATION POLYMERS; 3-PYRID-3-YLBENZOIC ACID;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new pyridinecarboxylato-bridged coordination polymers {[Sm(3,4-pbc)(3)(H2O)(2)]center dot H2O}(n){1} (3,4-pbc=3-pyrid-4-ylbenzoic acid)has been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single crystal X-ray analyses reveal that the carboxylate groups of 3,4-pbc ligands adopt two coordinated mode: bis-monodentate (mu(2)-eta(1):eta(1)) and bidentate chelating (mu(1)-eta(1):eta(1)). Hydrogen bonding interactions are found in compound {[Sm(3,4-pbc)(3)(H2O)(2)]center dot H2O}(n), which further extend and stabilize the coordination motifs.
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页码：1368 / 1370
页数：3
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