Counterions at charged cylinders: Criticality and universality beyond mean-field theory

被引:53
|
作者
Naji, A [1 ]
Netz, RR [1 ]
机构
[1] Tech Univ, Dept Phys, D-85748 Garching, Germany
关键词
D O I
10.1103/PhysRevLett.95.185703
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The counterion-condensation transition at charged cylinders is studied using Monte Carlo simulations. Employing logarithmically rescaled radial coordinates, large system sizes are tractable and the critical behavior is determined by a combined finite-size and finite-ion-number analysis. Critical counterion localization exponents are introduced and found to be in accord with mean-field theory both in two (2D) and three (3D) dimensions. In 3D, the heat capacity shows a universal jump at the transition, while in 2D, it consists of discrete peaks where single counterions successively condense.
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页数:4
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