Counterions at charged cylinders: Criticality and universality beyond mean-field theory

被引:53
作者
Naji, A [1 ]
Netz, RR [1 ]
机构
[1] Tech Univ, Dept Phys, D-85748 Garching, Germany
关键词
D O I
10.1103/PhysRevLett.95.185703
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The counterion-condensation transition at charged cylinders is studied using Monte Carlo simulations. Employing logarithmically rescaled radial coordinates, large system sizes are tractable and the critical behavior is determined by a combined finite-size and finite-ion-number analysis. Critical counterion localization exponents are introduced and found to be in accord with mean-field theory both in two (2D) and three (3D) dimensions. In 3D, the heat capacity shows a universal jump at the transition, while in 2D, it consists of discrete peaks where single counterions successively condense.
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页数:4
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共 24 条
[1]   THE COUNTERION DISTRIBUTION IN SOLUTIONS OF ROD-SHAPED POLYELECTROLYTES [J].
ALFREY, T ;
BERG, PW ;
MORAWETZ, H .
JOURNAL OF POLYMER SCIENCE, 1951, 7 (05) :543-547
[2]   INTERACTIONS OF SODIUM-IONS WITH POLY-ELECTROLYTES OF VARYING CHARGE-DENSITY [J].
ANDER, P ;
KARDAN, M .
MACROMOLECULES, 1984, 17 (11) :2431-2436
[3]  
Cardy J., 1996, SCALING RENORMALIZAT
[4]   Counterion distribution around DNA probed by solution X-ray scattering [J].
Das, R ;
Mills, TT ;
Kwok, LW ;
Maskel, GS ;
Millett, IS ;
Doniach, S ;
Finkelstein, KD ;
Herschlag, D ;
Pollack, L .
PHYSICAL REVIEW LETTERS, 2003, 90 (18) :4
[5]   Structural investigations of DNA-polycation complexes [J].
DeRouchey, J ;
Netz, RR ;
Rädler, JO .
EUROPEAN PHYSICAL JOURNAL E, 2005, 16 (01) :17-28
[6]   Fraction of condensed counterions around a charged rod: Comparison of Poisson-Boltzmann theory and computer simulations [J].
Deserno, M ;
Holm, C ;
May, S .
MACROMOLECULES, 2000, 33 (01) :199-206
[7]   Counterion phase transitions in dilute polyelectrolyte solutions [J].
Deshkovski, A ;
Obukhov, S ;
Rubinstein, M .
PHYSICAL REVIEW LETTERS, 2001, 86 (11) :2341-2344
[8]   THE POTENTIAL OF AN INFINITE ROD-LIKE MOLECULE AND THE DISTRIBUTION OF THE COUNTER IONS [J].
FUOSS, RM ;
KATCHALSKY, A ;
LIFSON, S .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1951, 37 (09) :579-589
[9]   Distribution of counterions near discretely charged planes and rods [J].
Henle, ML ;
Santangelo, CD ;
Patel, DM ;
Pincus, PA .
EUROPHYSICS LETTERS, 2004, 66 (02) :284-290
[10]   PAINLEVE-III AND MANNINGS COUNTERION CONDENSATION [J].
KHOLODENKO, AL ;
BEYERLEIN, AL .
PHYSICAL REVIEW LETTERS, 1995, 74 (23) :4679-4681