Aromatics hydrogenation over supported platinum catalysts: The influence of sulfur on the kinetics of toluene hydrogenation over Pt/Y-zeolite catalysts.

被引:0
|
作者
Bergem, H
Blekkan, EA
Holmen, A
机构
来源
HYDROTREATMENT AND HYDROCRACKING OF OIL FRACTIONS | 1997年 / 106卷
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper we report some experimental results with Pt/Y-zeolite catalysts, using the hydrogenation of toluene as a model for aromatics hydrogenation in hydrotreating. The hydrogenation of toluene was studied under conditions close to realistic industrial conditions. The findings include a complex temperature behaviour with a maximum in the reaction rate close to 325 degrees C. The pressure dependence of the rate with respect to toluene and H-2 was found to be sensitive to the level of sulfur in the liquid feed.
引用
收藏
页码:391 / 401
页数:11
相关论文
共 50 条
  • [1] TOLUENE HYDROGENATION OVER SUPPORTED PLATINUM CATALYSTS
    LIN, SD
    VANNICE, MA
    HERRMANN, JM
    WANG, D
    APESTEQUIA, C
    DUPREZ, D
    FIGUERAS, F
    CONNER, WC
    KIPERMAN, SL
    HALL, WK
    BLACKMOND, DG
    GRUNERT, W
    BUTT, JB
    SCHULZ, H
    STUDIES IN SURFACE SCIENCE AND CATALYSIS, 1993, 75 : 861 - 874
  • [2] Hydrogenation of toluene over supported pt and pd catalysts: Influence of structural factors on the sulfur tolerance
    Thomas, K
    Binet, C
    Chevreau, T
    Cornet, D
    Gilson, JP
    JOURNAL OF CATALYSIS, 2002, 212 (01) : 63 - 75
  • [3] Hydrogenation of aromatics over supported Pt-Pd catalysts
    Pawelec, B
    Mariscal, R
    Navarro, RM
    van Bokhorst, S
    Rojas, S
    Fierro, JLG
    APPLIED CATALYSIS A-GENERAL, 2002, 225 (1-2) : 223 - 237
  • [5] Sulfur and nitrogen sensitivity of supported Pt hydrogenation catalysts.
    Lercher, JA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U592 - U592
  • [6] Gas-phase hydrogenation of butyronitrile over supported platinum catalysts.
    McMillan, Scott T.
    Agrawal, Pradeep K.
    Industrial and Engineering Chemistry Research, 1988, 27 (02): : 243 - 248
  • [7] HYDROGENATION OF AROMATIC-HYDROCARBONS OVER SUPPORTED PT CATALYSTS .2. TOLUENE HYDROGENATION
    LIN, SD
    VANNICE, MA
    JOURNAL OF CATALYSIS, 1993, 143 (02) : 554 - 562
  • [8] KINETICS OF PROPENE HYDROGENATION OVER PLATINUM AND PLATINUM TIN CATALYSTS SUPPORTED ON POLYAMIDE
    GALVAGNO, S
    STAITI, P
    ANTONUCCI, P
    DONATO, A
    PIETROPAOLO, R
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 : 2605 - 2612
  • [9] HYDROGENATION OF CARBON MONOXIDE OVER SUPPORTED RHODIUM CATALYSTS.
    Arai, Hiromichi
    Uchida, Masayuki
    Tominaga, Hiroo
    Energy developments in Japan, 1981, 3 (04): : 387 - 399
  • [10] Acetic acid hydrogenation over Pt and Fe catalysts.
    Vannice, MA
    Rachmady, W
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : C7 - C8