A unique fourfold intramolecular hydrogen bonding stabilises the structure of trans-bis(2-amino-5,7-dimethyl[1,2,4]triazolo[1,5-α]pyrimidine-N3)-aquatrichlororuthenium(III) monohydrate

被引：0

作者：

Velders, AH

Ugozzoli, F

Biagini-Cingi, M

Manotti-Lanfredi, AM

Haasnoot, JG

Reedijk, J

机构：

[1] Leiden Univ, Gorlaeus Labs, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[2] Univ Parma, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy

[3] CNR, Ctr Studio Strutturist Diffrattometr, I-43100 Parma, Italy

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 1999年 / 02期

关键词：

ruthenium; nitrogen heterocycles; hydrogen bonds; antitumor agents; crystal structures;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray structure of the potential antitumour complex trans-[RuCl3(H2O) (admtp)(2)] ? H2O (admtp = 2-amino-5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine) shows unique and very interesting intramolecular hydrogen-bonding properties with the non-bridgehead pyrimidinic nitrogen atom of admtp acting as hydrogen acceptor and the amino group acting as hydrogen donor.

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页码：213 / 215

页数：3

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