Prospects of Value-Added Chemicals and Hydrogen via Electrolysis

被引：78

作者：

Garlyyev, Batyr ^{[1
]}

Xue, Song ^{[1
]}

Fichtner, Johannes ^{[1
]}

Bandarenka, Aliaksandr S. ^{[1
]}

Andronescu, Corina ^{[2
,3
]}

机构：

[1] Tech Univ Munich, Dept Phys, Phys Energy Convers & Storage, James Franck Str 1, D-85748 Garching, Germany

[2] Univ Duisburg Essen, Tech Chem 3, Fac Chem, Carl Benz Str 199, D-47057 Duisburg, Germany

[3] Univ Duisburg Essen, CENIDE, Carl Benz Str 199, D-47057 Duisburg, Germany

来源：

CHEMSUSCHEM | 2020年 / 13卷 / 10期

关键词：

alcohols; electrolysis; electrooxidation; electrosynthesis; peroxide production; ELECTROCATALYTIC OXIDATION; WATER OXIDATION; ELECTROCHEMICAL OXIDATION; OXYGEN EVOLUTION; ELECTROOXIDATION; ALCOHOLS; GLYCEROL; ETHANOL; PEROXIDE; BIOMASS;

D O I：

10.1002/cssc.202000339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cost is a major drawback that limits the industrial-scale hydrogen production through water electrolysis. The overall cost of this technology can be decreased by coupling the electrosynthesis of value-added chemicals at the anode side with electrolytic hydrogen generation at the cathode. This Minireview provides a directory of anodic oxidation reactions that can be combined with cathodic hydrogen generation. The important parameters for selecting the anodic reactions, such as choice of catalyst material and its selectivity towards specific products are elaborated in detail. Furthermore, various novel electrolysis cell architectures for effortless separation of value-added products from hydrogen gas are described.

引用

页码：2513 / 2521

页数：9

共 71 条

[1] Transition metal oxides in the electrocatalytic oxidation of methanol and ethanol on noble metal nanoparticles [J].