Facile Sonochemical Synthesis of Flexible Fe-Based Metal-Organic Frameworks and Their Efficient Removal of Organic Contaminants from Aqueous Solutions

被引：42
作者：
Lee, Ji Hwan [1 ]
Ahn, Yongjun [1 ]
Kwak, Seung-Yeop [1 ,2 ,3 ]
机构：
[1] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 08826, South Korea
[2] Seoul Natl Univ, Res Inst Adv Mat RIAM, Seoul 08826, South Korea
[3] Seoul Natl Univ, Inst Engn Res, Seoul 08826, South Korea
来源：
ACS OMEGA | 2022年
关键词：
BISPHENOL-A; ADSORPTIVE REMOVAL; BETA-CYCLODEXTRIN; METHYLENE-BLUE; MIL-53; FE; WASTE-WATER; NANOCOMPOSITE; CARBON; MOFS; DYE;
D O I：
10.1021/acsomega.2c01068
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An iron-based metal-organic framework, MIL-53(Fe), was synthesized via the simple sonochemical method, which is a facial and fast strategy, and their adsorption performance for organic contaminants removal from aqueous solutions was studied. The crystal structure and morphology analysis indicate that the sonochemical synthesis of MIL-53(Fe) particles was faster than the solvothermal preparation method, showing high crystallinity with a downsized hexagonal bipyramid shape. Furthermore, the prepared MIL-53(Fe) exhibited enhanced adsorption capability for the organic dyes compared to metalorganic framework prepared via the solvothermal method and showed excellent maximum adsorption capability for the methyl orange removal from aqueous solutions. Based on the superior adsorption properties and facile synthesis, MIL-53(Fe) prepared by ultrasound irradiation has a potential application for an efficient, economic, and ecofriendly wastewater purification process.
引用
收藏
页码：23213 / 23222
页数：10
相关论文
共 60 条
[1]   Synthesis of MIL-100(Fe)@MIL-53(Fe) as a novel hybrid photocatalyst and evaluation photocatalytic and photoelectrochemical performance under visible light irradiation [J].
Abdpour, Soheil ;
Kowsari, Elaheh ;
Moghaddam, Mohammad Reza Alavi .
JOURNAL OF SOLID STATE CHEMISTRY, 2018, 262 :172-180
[2]   Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: Kinetic, isotherm and mechanism analysis [J].
Ai, Lunhong ;
Zhang, Chunying ;
Liao, Fang ;
Wang, Yao ;
Li, Ming ;
Meng, Lanying ;
Jiang, Jing .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 198 :282-290
[3]   Selective removal of dual dyes from aqueous solutions using a metal organic framework (MIL-53(Al)) [J].
Al Sharabati, Miral ;
Sabouni, Rana .
POLYHEDRON, 2020, 190
[4]   Remediation of phenol-contaminated water by adsorption using poly(methyl methacrylate) (PMMA) [J].
Al-Muhtaseb, Ala'a H. ;
Ibrahim, Khalid A. ;
Albadarin, Ahmad B. ;
Ali-Khashman, Omar ;
Walker, Gavin M. ;
Ahmad, Mohammad N. M. .
CHEMICAL ENGINEERING JOURNAL, 2011, 168 (02) :691-699
[5]   MOF derived porous carbon-Fe3O4 nanocomposite as a high performance, recyclable environmental superadsorbent [J].
Banerjee, Abhik ;
Gokhale, Rohan ;
Bhatnagar, Sumit ;
Jog, Jyoti ;
Bhardwaj, Monika ;
Lefez, Benoit ;
Hannoyer, Beatrice ;
Ogale, Satishchandra .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (37) :19694-19699
[6]   Screening of bio-compatible metal-organic frameworks as potential drug carriers using Monte Carlo simulations [J].
Bernini, Maria C. ;
Fairen-Jimenez, David ;
Pasinetti, Marcelo ;
Ramirez-Pastor, Antonio J. ;
Snurr, Randall Q. .
JOURNAL OF MATERIALS CHEMISTRY B, 2014, 2 (07) :766-774
[7]   Adsorptive removal of bisphenol A (BPA) from aqueous solution: A review [J].
Bhatnagar, Amit ;
Anastopoulos, Loannis .
CHEMOSPHERE, 2017, 168 :885-902
[8]   Boosting Photocatalytic Performance in Mixed-Valence MIL-53(Fe) by Changing FeII/FeIII Ratio [J].
Chen, Hui ;
Liu, Yutang ;
Cai, Tao ;
Dong, Wanyue ;
Tang, Lin ;
Xia, Xinnian ;
Wang, Longlu ;
Li, Tao .
ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (32) :28791-28800
[9]   Excavating hidden adsorption sites in metal-organic frameworks using rational defect engineering [J].
Chong, Sanggyu ;
Thiele, Gunther ;
Kim, Jihan .
NATURE COMMUNICATIONS, 2017, 8
[10]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
123456