Effect of shear rate and pressure on the crystallization of PP nanocomposites and PP/PET polymer blend nanocomposites

被引：15

作者：

Sangroniz, Leire ^{[1
,2
]}

van Drongelen, Martin ^{[3
]}

Cardinaels, Ruth ^{[4
]}

Santamaria, Antxon ^{[1
,2
]}

Peters, Gerrit W. M. ^{[4
]}

Mueller, Alejandro J. ^{[1
,2
,5
]}

机构：

[1] Univ Basque Country, UPV EHU, Fac Chem, POLYMAT, Paseo Manuel de Lardizabal 3, Donostia San Sebastian 20018, Spain

[2] Univ Basque Country, UPV EHU, Fac Chem, Polymer Sci & Technol Dept, Paseo Manuel de Lardizabal 3, Donostia San Sebastian 20018, Spain

[3] Univ Twente, Fac Engn Technol, Chair Prod Technol, Drienerlolaan 5, NL-7255 NB Enschede, Netherlands

[4] Eindhoven Univ Technol, Dept Mech Engn, Polymer Technol, PB 513, NL-5600 MB Eindhoven, Netherlands

[5] Basque Fdn Sci, IKERBASQUE, Bilbao, Spain

来源：

POLYMER | 2020年 / 186卷 / 186期

关键词：

Nanocomposites; Polymer blend nanocomposites; Crystallization; Pressure; Shear flow; FLOW-INDUCED CRYSTALLIZATION; ISOTACTIC POLYPROPYLENE; COOLING RATE; MULTIPHASE CRYSTALLIZATION; MORPHOLOGY; PARTICLES; RHEOLOGY; QUANTIFICATION; NUCLEATION; DISPERSION;

D O I：

10.1016/j.polymer.2019.121950

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of shear flow on the crystallization of homopolymers has been widely studied, however more complex systems such as nanocomposites or polymer blends nanocomposites (PBNANOs) have received less attention. In this work, the effect of pressure and shear flow on the crystallization process of polypropylene-based nanocomposites and polypropylene/polyethylene terephthalate PBNANOs have been studied employing dilatometry (PVT), X-ray, rheology, and DSC. The material systems used allow studying the effect of shear in the presence of nanoparticles that do not have a nucleating effect, as well as the combined effect of shear and nucleating nanoparticles. Nucleating nanoparticles increase the crystallization temperature more significantly because of the combined effect of nucleation and flow. For carbon nanotubes, nucleation is more pronounced due to stronger interactions with PP chains, as demonstrated by rheological measurements. For PBNANOs the effect of shear on crystallization is more significant due to the higher amount of available surfaces.

引用

页数：14

共 46 条

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