Unexpected effect of citrate ions on the corrosion process of carbon steel in alkaline solutions

被引：24

作者：

Toujas, S. ^{[1
]}

Vazquez, M. ^{[1
]}

Valcarce, M. B. ^{[1
]}

机构：

[1] Univ Nacl Mar del Plata, CONICET, Fac Ingn, Div Electroquim Aplicada,INTEMA, JB Justo 4302,B7608FDQ, Mar Del Plata, Buenos Aires, Argentina

来源：

CORROSION SCIENCE | 2017年 / 128卷

关键词：

Steel reinforced concrete; Cyclic voltammetry; Raman spectroscopy; Weight-loss; Alkaline corrosion; Passive films; CHLORIDE-INDUCED CORROSION; RING-DISK ELECTRODE; REINFORCING STEEL; ELECTROCHEMICAL-BEHAVIOR; RAMAN-SPECTROSCOPY; PORE SOLUTION; IRON; CONCRETE; INHIBITORS; PASSIVITY;

D O I：

10.1016/j.corsci.2017.08.018

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effect of citrate ions on the passive film stability on carbon steel, at pH 13, was evaluated. The study involved cyclic voltammograms, potentiodynamic polarization curves, micro-Raman spectroscopy and weight loss tests. No beneficial effects on delaying or inhibiting pitting were observed in the presence of citrate ions. Organic compounds with carboxylate groups are promising corrosion inhibitors. However, the incorporation of citrate ions is clearly harmful to carbon steel in alkaline solutions and accelerates the corrosion process. Citrate ions adsorption is not observed on passive steel. Instead, citrate ions can unexpectedly dissolve the passive layer facilitating the corrosion process.

引用

页码：94 / 99

页数：6

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