Reduced electrode polarization at electrode and analyte interface in impedance spectroscopy using carbon paste and paper

The double layer present at the interface of an electrode and an analyte causes electrode polarization (EP) in impedance spectroscopy, which hinders acquiring the actual impedance of biological samples at a lower frequency region. In this work, a novel carbon paste (CP) electrode material prepared by mixing the pencil graphite powder with transparent glue has been reported to reduce the EP by depositing its two coplanar electrodes on a chromatography paper substrate. Furthermore, two other devices having silver paste and pencil electrodes on the chromatography paper have been fabricated, analyzed for the EP, and compared with the CP electrode. The EP is quantified by fitting the impedance data to an equivalent electrical circuit having double layer capacitance as a constant phase element, and the CP electrode shows the lowest EP among the electrodes. The cyclic voltammetry analysis reveals blocking electrode property of the CP, which diminishes dc current flow at the electrode/electrolyte interface. Furthermore, the chromatography paper is found to increase the effective surface area of the deposited electrode by enhancing its surface roughness, which helps reduce the EP.