Ruddlesden-Popper faults in LaNiO3/LaAlO3 superlattices

被引:32
作者
Detemple, E. [1 ]
Ramasse, Q. M. [2 ]
Sigle, W. [1 ]
Cristiani, G. [3 ]
Habermeier, H. -U. [3 ]
Keimer, B. [3 ]
van Aken, P. A. [1 ]
机构
[1] Max Planck Inst Intelligent Syst, D-70569 Stuttgart, Germany
[2] STFC Daresbury, SuperSTEM Lab, Warrington WA4 4AD, Cheshire, England
[3] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
关键词
OXIDE;
D O I
10.1063/1.4731249
中图分类号
O59 [应用物理学];
学科分类号
摘要
Scanning transmission electron microscopy in combination with electron energy-loss spectroscopy is used to study LaNiO3/LaAlO3 superlattices grown on (La,Sr) AlO4 with varying single-layer thicknesses, which are known to control their electronic properties. The microstructure of the films is investigated on the atomic level and the role of observed defects is discussed in the context of the different properties. Two types of Ruddlesden-Popper faults are found, which are either two or three dimensional. The common planar Ruddlesden-Popper fault is induced by steps on the substrate surface. In contrast, the three-dimensionally arranged Ruddlesden-Popper fault, whose size is in the nanometer range, is caused by the formation of local stacking faults during film growth. Furthermore, the interfaces of the superlattices are found to show different sharpness, but the microstructure does not depend substantially on the single-layer thickness. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4731249]
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页数:5
相关论文
共 24 条
[1]   Chemistry of Ruddlesden-Popper planar faults at a ferroelectric-ferromagnet perovskite interface [J].
Arredondo, M. ;
Weyland, M. ;
Hambe, M. ;
Ramasse, Q. M. ;
Munroe, P. ;
Nagarajan, V. .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (08)
[2]   Dimensionality Control of Electronic Phase Transitions in Nickel-Oxide Superlattices [J].
Boris, A. V. ;
Matiks, Y. ;
Benckiser, E. ;
Frano, A. ;
Popovich, P. ;
Hinkov, V. ;
Wochner, P. ;
Castro-Colin, M. ;
Detemple, E. ;
Malik, V. K. ;
Bernhard, C. ;
Prokscha, T. ;
Suter, A. ;
Salman, Z. ;
Morenzoni, E. ;
Cristiani, G. ;
Habermeier, H. -U. ;
Keimer, B. .
SCIENCE, 2011, 332 (6032) :937-940
[3]   Orbital order and possible superconductivity in LaNiO3/LaMO3 superlattices [J].
Chaloupka, Jiri ;
Khaliullin, Giniyat .
PHYSICAL REVIEW LETTERS, 2008, 100 (01)
[4]   Polarity-driven nickel oxide precipitation in LaNiO3-LaAlO3 superlattices [J].
Detemple, E. ;
Ramasse, Q. M. ;
Sigle, W. ;
Cristiani, G. ;
Habermeier, H. -U. ;
Benckiser, E. ;
Boris, A. V. ;
Frano, A. ;
Wochner, P. ;
Wu, M. ;
Keimer, B. ;
van Aken, P. A. .
APPLIED PHYSICS LETTERS, 2011, 99 (21)
[5]   Structural dependence of microwave dlielectric properties of SrRAIO4 (R = Sm, Nd, La) ceramics:: Crystal structure refinement and infrared reflectivity study [J].
Fan, Xie Cheng ;
Chen, Xiang Ming ;
Liu, Xiao Qiang .
CHEMISTRY OF MATERIALS, 2008, 20 (12) :4092-4098
[6]   NEUTRON-DIFFRACTION STUDY OF RNIO3 (R = LA,PR,ND,SM) - ELECTRONICALLY INDUCED STRUCTURAL-CHANGES ACROSS THE METAL-INSULATOR-TRANSITION [J].
GARCIAMUNOZ, JL ;
RODRIGUEZCARVAJAL, J ;
LACORRE, P ;
TORRANCE, JB .
PHYSICAL REVIEW B, 1992, 46 (08) :4414-4425
[7]   Electronic structure of nickelates: From two-dimensional heterostructures to three-dimensional bulk materials [J].
Hansmann, P. ;
Toschi, A. ;
Yang, Xiaoping ;
Andersen, O. K. ;
Held, K. .
PHYSICAL REVIEW B, 2010, 82 (23)
[8]  
Hwang HY, 2012, NAT MATER, V11, P103, DOI [10.1038/nmat3223, 10.1038/NMAT3223]
[9]   Asymmetric interface profiles in LaVO3/SrTiO3 heterostructures grown by pulsed laser deposition [J].
Kourkoutis, L. Fitting ;
Muller, D. A. ;
Hotta, Y. ;
Hwang, H. Y. .
APPLIED PHYSICS LETTERS, 2007, 91 (16)
[10]   Origin of antiphase domain boundaries and their effect on the dielectric constant of Ba0.5Sr0.5TiO3 films grown on MgO substrates [J].
Li, H ;
Zheng, H ;
Salamanca-Riba, L ;
Ramesh, R ;
Naumov, I ;
Rabe, K .
APPLIED PHYSICS LETTERS, 2002, 81 (23) :4398-4400