Synthesis and crystal structure of a 2-D yttrium coordination network with propylenediamine-N,N,N′,N′-tetraacetic acid

被引:5
|
作者
Gao, Jingqun [1 ]
Li, Dan [1 ]
Wang, Jun [1 ]
Jin, Xudong [1 ]
Kang, Pingli [1 ]
Wu, Tong [1 ]
Li, Kai [1 ]
Zhang, Xiangdong [1 ]
机构
[1] Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrothermal synthesis; Y(III); pdta; (H(4)pdta; propylenediamine-N; N; N '-tetraacetic acid); 2-D structure; IN-VITRO; 9-COORDINATE; 8-COORDINATE; COMPLEX; AGENTS; Y-90; MRI; EU;
D O I
10.1080/00958972.2011.594163
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A 2-D binuclear coordination polymer, {[Y-III(Hpdta)(H2O)](2)center dot 6H(2)O}(n) (H(4)pdta = propylenediamine-N,N,N',N'-tetraacetic acid), has been synthesized through direct hydrothermal reaction and characterized by infrared spectrum and thermal analysis. Single-crystal X-ray diffraction reveals that Y(III) is eight-coordinate of almost standard square antiprismatic polyhedron.
引用
收藏
页码:2284 / 2291
页数:8
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