Metal-Catalyzed/Mediated Aromatic C-H Bond Trifluoromethylation

被引：2

作者：

Kamei, Toshiyuki

机构：

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2012年 / 70卷 / 07期

关键词：

PERFLUOROALKANESULFONYL CHLORIDES; ARENES; COMPLEX; PERFLUOROALKYLATION; HETEROARENES; CATALYSIS;

D O I：

10.5059/yukigoseikyokaishi.70.756

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trifluoromethyl group is one of the important groups in medicinal chemistry. In 2010, Yu and Sanford reported the Pd-catalyzed aromatic C-H bond trifluoromethylation with the aid of directing groups. With these reports as a turning point, the studies on this field have been developed in a couple of years. This review describes the recent advances in aromatic C-H bond trifluoromethylation catalyzed/mediated by transition metal reagents.

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页码：756 / 757

页数：2

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