Sulfate Radical and Its Application in Decontamination Technologies

被引:507
作者
Zhang, Bo-Tao [1 ,2 ]
Zhang, Yang [1 ]
Teng, Yanguo [1 ]
Fan, Maohong [2 ]
机构
[1] Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China
[2] Univ Wyoming, Dept Chem & Petr Engn, Laramie, WY 82071 USA
基金
中国国家自然科学基金;
关键词
heterogeneous catalysis oxidation; persulfate; peroxymonosulfate; sulfate radical; decontamination technologies; ACTIVATED PERSULFATE OXIDATION; HETEROGENEOUS CATALYTIC-OXIDATION; TERT-BUTYL ETHER; HOLLOW TITANIA PHOTOCATALYST; SUPPORTED COBALT CATALYSTS; HIGHLY EFFICIENT CATALYSTS; REDUCED GRAPHENE OXIDE; PRESSURIZED HOT-WATER; IN-SITU REMEDIATION; WET AIR OXIDATION;
D O I
10.1080/10643389.2014.970681
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This article gives a broad overview about the status and progress of the sulfate radical-based decontamination technologies. Peroxymonosulfate or persulfate can be activated by energy or a catalyzer to form sulfate radical for rapid and effective degradation of contaminants in homogenous systems. Sulfate radical-based heterogeneous catalysis oxidation has been a major research focus since 2005 because solid catalysts are stable, cost-effective, and easy to recover. The application of sulfate radical in other decontamination technologies and the mechanisms involved are also described and discussed. The main points are summarized and the directions of future researches are suggested in the last section.
引用
收藏
页码:1756 / 1800
页数:45
相关论文
共 185 条
[1]   Ultrasound-induced aqueous removal of nitric oxide from flue gases: Effects of sulfur dioxide, chloride, and chemical oxidant [J].
Adewuyi, Yusuf G. ;
Owusu, Samuel O. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (38) :11098-11107
[2]   Removal of Nitric Oxide by Aqueous Sodium Persulfate Simultaneously Activated by Temperature and Fe2+ in a Lab-scale Bubble Reactor [J].
Adewuyi, Yusuf G. ;
Sakyi, Nana Y. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (41) :14687-14697
[3]   Simultaneous Absorption and Oxidation of Nitric Oxide and Sulfur Dioxide by Aqueous Solutions of Sodium Persulfate Activated by Temperature [J].
Adewuyi, Yusuf G. ;
Sakyi, Nana Y. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (33) :11702-11711
[4]   Persulfate activation by subsurface minerals [J].
Ahmad, Mushtaque ;
Teel, Amy L. ;
Watts, Richard J. .
JOURNAL OF CONTAMINANT HYDROLOGY, 2010, 115 (1-4) :34-45
[5]   NF-TiO2 photocatalysis of amitrole and atrazine with addition of oxidants under simulated solar light: Emerging synergies, degradation intermediates, and reusable attributes [J].
Andersen, Joel ;
Pelaez, Miguel ;
Guay, Lisa ;
Zhang, Zhaohong ;
O'Shea, Kevin ;
Dionysiou, Dionysios D. .
JOURNAL OF HAZARDOUS MATERIALS, 2013, 260 :569-575
[6]   Transition metal/UV-based advanced oxidation technologies for water decontamination [J].
Anipsitakis, GP ;
Dionysiou, DD .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 54 (03) :155-163
[7]   Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt [J].
Anipsitakis, GP ;
Dionysiou, DD .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (20) :4790-4797
[8]   Heterogeneous activation of oxone using Co3O4 [J].
Anipsitakis, GP ;
Stathatos, E ;
Dionysiou, DD .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (27) :13052-13055
[9]   Radical generation by the interaction of transition metals with common oxidants [J].
Anipsitakis, GP ;
Dionysiou, DD .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (13) :3705-3712
[10]   Degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) using cobalt-peroxymonosulfate in Fenton-like process [J].
Bandala, Erick R. ;
Pelaez, Miguel A. ;
Dionysiou, Dionysios D. ;
Gelover, Silvia ;
Garcia, Javier ;
Macias, Diana .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 186 (2-3) :357-363