Charge transport in metal-organic frameworks for electronics applications

被引:41
作者
Calvo, James J. [1 ]
Angel, Sydney M. [1 ]
So, Monica C. [1 ]
机构
[1] Calif State Univ Chico, Dept Chem & Biochem, Chico, CA 95973 USA
关键词
TUNABLE ELECTRICAL-CONDUCTIVITY; THIN-FILMS; SENSOR; DEVICES; FLUORESCENCE; CHALLENGES; REDUCTION; CRYSTALS; MOBILITY; ROADMAP;
D O I
10.1063/1.5143590
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In recent years, functional electronic nanomaterials have made significant strides from advancements in the interplay of physics, chemistry, materials science, and computational research. However, synthetically tunable electronic materials are a long-standing, but elusive, technological goal. More recently, metal-organic frameworks (MOFs), a class of nanoporous, hybrid inorganic-organic crystalline solids, have garnered attention as a novel class of electronic nanomaterials. The aim of this perspective is to (i) highlight the charge transport behavior of recently discovered (2017-2019) electronic MOFs and (ii) recommend future directions for improvement of intrinsically and extrinsically conductive MOFs for MOF-based electronics.
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页数:10
相关论文
共 83 条
[1]   Luminescent metal-organic frameworks [J].
Allendorf, M. D. ;
Bauer, C. A. ;
Bhakta, R. K. ;
Houk, R. J. T. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1330-1352
[2]   A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions [J].
Allendorf, Mark D. ;
Schwartzberg, Adam ;
Stavila, Vitalie ;
Talin, A. Alec .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (41) :11372-11388
[3]  
Ashcroft N. W., 1976, Solid State Physics, P243
[4]   Electron delocalization and charge mobility as a function of reduction in a metal-organic framework [J].
Aubrey, Michael L. ;
Wiers, Brian M. ;
Andrews, Sean C. ;
Sakurai, Tsuneaki ;
Reyes-Lillo, Sebastian E. ;
Hamed, Samia M. ;
Yu, Chung-Jui ;
Darago, Lucy E. ;
Mason, Jarad A. ;
Baeg, Jin-Ook ;
Grandjean, Fernande ;
Long, Gary J. ;
Seki, Shu ;
Neaton, Jeffrey B. ;
Yang, Peidong ;
Long, Jeffrey R. .
NATURE MATERIALS, 2018, 17 (07) :625-+
[5]   Liquid-Phase Epitaxially Grown Metal-Organic Framework Thin Films for Efficient Tandem Catalysis Through Site-Isolation of Catalytic Centers [J].
Beyzavi, M. Hassan ;
Vermeulen, Nicolaas A. ;
Zhang, Kainan ;
So, Monica ;
Kung, Chung-Wei ;
Hupp, Joseph T. ;
Farha, Omar K. .
CHEMPLUSCHEM, 2016, 81 (08) :708-713
[6]   Metal-Organic Frameworks as Active Materials in Electronic Sensor Devices [J].
Campbell, Michael G. ;
Dinca, Mircea .
SENSORS, 2017, 17 (05)
[7]   Cu3(hexaiminotriphenylene)2: An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing [J].
Campbell, Michael G. ;
Sheberla, Dennis ;
Liu, Sophie F. ;
Swager, Timothy M. ;
Dinca, Mircea .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (14) :4349-4352
[8]   A multifunctional three-dimensional uninodal eight-connected metal-organic framework based on pentanuclear cadmium subunits: New topology, fluorescent and NLO properties [J].
Cheng, Lin ;
Hu, Huayou ;
Zhang, Liming ;
Gou, Shaohua .
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 15 :202-207
[9]   Highly sensitive and selective SO2 MOF sensor: the integration of MFM-300 MOF as a sensitive layer on a capacitive interdigitated electrode [J].
Chernikova, Valeriya ;
Yassine, Omar ;
Shekhah, Osama ;
Eddaoudi, Mohamed ;
Salama, Khaled N. .
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (14) :5550-5554
[10]   Room Temperature Metallic Conductivity in a Metal-Organic Framework Induced by Oxidation [J].
Clough, Andrew J. ;
Orchanian, Nicholas M. ;
Skelton, Jonathan M. ;
Neer, Abbey J. ;
Howard, Sebastian A. ;
Downes, Courtney A. ;
Piper, Louis F. J. ;
Walsh, Aron ;
Melot, Brent C. ;
Marinescu, Smaranda C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (41) :16323-16330