Physicochemical study of water-soluble C60(OH)24 fullerenol

被引：23
|
作者：
Sharoyko, Vladimir V. [1 ,2 ]
Ageev, Sergei, V [1 ,2 ]
Meshcheriakov, Anatolii A. [1 ,2 ]
Akentiev, Alexander, V [1 ]
Noskov, Boris A. [1 ]
Rakipov, Ilnaz T. [3 ]
Charykov, Nikolay A. [4 ]
Kulenova, Natalya A. [5 ]
Shaimardanova, Botagoz K. [5 ]
Podolsky, Nikita E. [1 ]
Semenov, Konstantin N. [1 ,2 ,6 ]
机构：
[1] St Petersburg State Univ, Inst Chem, Univ Skii Prospect 26, St Petersburg 198504, Russia
[2] Pavlov First St Petersburg State Med Univ, Lva Tolstogo Ulitsa 6-8, St Petersburg 197022, Russia
[3] Kazan Fed Univ, Dept Phys Chem, Kremlevskaya Ulitsa 18, Kazan 420008, Russia
[4] Tech Univ, St Petersburg State Technol Inst, Moskovskii Prospect 26, St Petersburg 190013, Russia
[5] D Serikbayev East Kazakhstan State Tech Univ, Ulitsa Serikbayeva 19, Ust Kamenogorsk 070000, Kazakhstan
[6] Almazov Natl Med Res Ctr, Akkuratova Ulitsa 2, St Petersburg 197341, Russia
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2020年 / 311卷
基金：
俄罗斯基础研究基金会;
关键词：
Fullerenol; Density; Speed of sound; Surface tension; HSA; Excess thermodynamic functions; DOXORUBICIN-INDUCED CARDIOTOXICITY; ISOTHERMAL KINETICS; RATS; SYSTEMS; SOLVENT;
D O I：
10.1016/j.molliq.2020.113360
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The article presents novel physicochemical data on C-60(OH)(24) aqueous solutions. Temperature and concentration dependencies of density (rho) and speed of sound (u) and surface tension (gamma) were obtained. Additionally, the study of human serum albumin (HSA) binding to C-60(OH)(24) fullerenol was conducted, and thermodynamic characteristics of C-60(OH)(24)-HSA binding were calculated. The obtained values of a binding constant demonstrate that the complexes of C-60(OH)(24) with HSA are stable and HSA can perform transport functions in the bloodstream. Finally, excess thermodynamic functions of C-60(OH)(24)-H2O binary system were calculated under the application of Virial Decomposition Asymmetric Model (VD-AS) and the boundaries of diffusion stability loss were determined. Aqueous solutions of C-60(OH)(20) are thermodynamically stable up to x(diff) = 6.0 . 10(-5). Further concentration increase leads to formation of third-order dusters with linear dimensions of thousands of nanometres and phase separation of the aqueous solution. (C) 2020 Elsevier B.V. All rights reserved.
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页数：10
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