Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation

被引：30

作者：

Momin, Aurelien ^{[2
]}

Bonnet, Fanny ^{[1
]}

Visseaux, Marc ^{[1
]}

Maron, Laurent ^{[3
]}

Takats, Josef ^{[4
]}

Ferguson, Michael J. ^{[4
]}

Le Goff, Xavier-Frederic ^{[2
]}

Nief, Francois ^{[2
]}

机构：

[1] Univ Lille Nord France, Ecole Natl Super Chim Lille, CNRS, Unite Catalyse & Chim Solide, Villeneuve Dascq, France

[2] Ecole Polytech, CNRS, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

[3] Univ Toulouse, Inst Natl Sci Appl, CNRS, Lab Phys & Chim Nanoobjets, Toulouse, France

[4] Univ Alberta, Dept Chem, Edmonton, AB, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 44期

关键词：

RING-OPENING POLYMERIZATION; ORGANOTHULIUM(II) COMPLEX; SAMARIUM; PHOSPHOLYL; CYCLOPENTADIENYL; REACTIVITY; REDUCTION; CHEMISTRY; NEODYMIUM;

D O I：

10.1039/c1cc15294g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new divalent thulium compound [Tm(BH4)(2)(DME)(2)] could be prepared by reduction of [Tm(BH4)(3)(THF)(3)] or from TmI2 and KBH4. It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH4)(THF)] by reaction with potassium tris(2-tBu-4-Me) pyrazolylborate (KTp(tBu,Me)). Both Tm-II compounds were found active as epsilon-caprolactone polymerisation catalysts.

引用

页码：12203 / 12205

页数：3

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