{N,N′-bis[3-methoxymethyl-5-methylsalicylidene]-(R,R)-1,2-diphenylene-diamino}nickel(II)

被引:2
作者
Wu, JC [1 ]
Tang, N
Yu, KB
机构
[1] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
[2] Chengdu Brand Chinese Acad Sci, Anal Ctr, Chengdu 610041, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词
D O I
10.1107/S1600536803021949
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, 6,6'-bis( methoxymethyl)-4,4'-dimethyl-2,2'-[ 1,2-diphenyl-1,2-ethanediylbis(nitrilomethylidyne)] diphenol, [Ni(C34H34N2O4)], there are two independent molecules per asymmetric unit; both have a twofold axis. These molecular structures are two rotamers in the presence of steric repulsions between the ether groups, and the coordination geometry around the Ni-II atom is slightly tetrahedrally distorted square planar. The rotamers are stacked alternately along the c axis.
引用
收藏
页码:M977 / M979
页数:3
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