2,5-Bis{2,2-bis[4-(dimethylamino)phenyl]ethenyl}-N,N′-diphenyl-N,N′-dipropylbenzene-1,4-diamine

被引：0

作者：

Schmitt, Volker ^{[1
]}

Schollmeyer, Dieter ^{[1
]}

Detert, Heiner ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, D-55099 Mainz, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

SOLVATOCHROMISM;

D O I：

10.1107/S160053681100910X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C60H68N6, was prepared by Horner olefination of a terephthaldialdehyde and a diarylmethyl phosphonate. There is one half-molecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinylene unit and the central ring is 36.79 (15)degrees, while those between the vinylene unit and the lateral phenyl rings are 53.04 (10) and 53.74 (9)degrees.

引用

页码：O876 / U528

页数：11

共 17 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2] Bis(pyridylvinyl)diaminobenzenes: synthesis, acidochromism and solvatochromism of the fluorescence [J].

Detert, H ;

Sugiono, E .

JOURNAL OF LUMINESCENCE, 2005, 112 (1-4) :372-376

[3]

Detert H, 2001, EUR J ORG CHEM, V2001, P2927

[4] CRYSTALLOGRAPHIC COMPUTER PROGRAMS FOR CDC-3300 [J].

DRAGER, M ;

GATTOW, G .

ACTA CHEMICA SCANDINAVICA, 1971, 25 (02) :761-&

[5] UNTERSUCHUNGEN UBER STILBENE .39. DIE WITTIG-REAKTION MIT PARA-HALOGENMETHYL-BENZALDEHYD [J].

DREFAHL, G ;

PLOTNER, G .

CHEMISCHE BERICHTE-RECUEIL, 1961, 94 (04) :907-914

[6]

Enraf-Nonius, 1989, CAD 4 SOFTW

[7]

HUTTEN PFC, 1999, J AM CHEM SOC, V121, P5910

[8] Localized excitation effect on dipole moments of oligophenylenevinylenes in their excited Franck-Condon state [J].

Nemkovich, N. A. ;

Detert, H. ;

Schmitt, V. .

CHEMICAL PHYSICS, 2010, 378 (1-3) :37-41

[9]

SCHMITT V, 2005, THESIS U MAINZ MAINZ

[10] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

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