Synthesis and Structures of Lithium Salts of Stannole Anions

被引：15

作者：

Saito, Masaichi ^{[1
]}

Kuwabara, Takuya ^{[1
]}

Ishimura, Kazuya ^{[2
]}

Nagase, Shigeru ^{[2
]}

机构：

[1] Saitama Univ, Grad Sch Sci & Engn, Dept Chem, Sakura Ku, Saitama 3388570, Japan

[2] Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2010年 / 83卷 / 07期

关键词：

MOLECULAR-ORBITAL METHODS; BASIS-SET; AROMATICITY; POLARIZATION; COMPLEXES; SANDWICH;

D O I：

10.1246/bcsj.20100057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Lithio-1-phenyl- and 1-lithio-1-trimethylsilylstannoles were synthesized and the corresponding lithium salts of stannole anions were characterized by X-ray diffraction analysis. The five-membered rings of the two lithium salts are planar with remarkable alternation of the C-C bonds, suggesting that they are both non-aromatic. Theoretical calculations are also carried out to discuss their electronic nature.

引用

页码：825 / 827

页数：3

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