Photocatalytic Degradation of 2,4-Dichlorophenol in Water Using MgAl Activated Hydrotalcites as Photocatalyst

被引:3
|
作者
Ramos-Ramirez, Esthela [1 ]
Gutierrez-Ortega, Norma [2 ]
Tzompantzi-Morales, Francisco [3 ]
Castillo-Rodriguez, Julio [3 ]
Barrera-Rodriguez, Arturo [4 ]
Del Angel, Gloria [3 ]
Gutierrez-Arzaluz, Mirella [3 ]
Perez-Hernandez, Raul [5 ]
del Pilar Guevara-Hornedo, Maria [1 ]
机构
[1] Univ Guanajuato, Div Ciencias Nat & Exactas, Dept Quim, Campus Guanajuato, Guanajuato 36050, Gto, Mexico
[2] Univ Guanajuato, Div Ingn, Dept Ingn Civil & Ambiental, Campus Guanajuato, Guanajuato 36000, Gto, Mexico
[3] Univ Autonoma Metropolitana Iztapalapa & Azcapotz, Div Ciencias Basicas & Ingn, Av San Rafael Atlixco 186, Ciudad De Mexico 09340, Mexico
[4] Univ Guadalajara, Ctr Univ Cienega, Av Univ 1115, Ocotlan 47820, Jal, Mexico
[5] Inst Nacl Invest Nucl, Dept Estudios Ambiente, Carretera Mexico Toluca La Marquesa S-N, Ocoyoacac 52750, Estado De Mexic, Mexico
关键词
Photocatalysis; Mixed oxides; Semiconductor; Hydrotalcite; Degradation; LAYERED DOUBLE HYDROXIDES; MIXED-METAL OXIDES; TOXICITY; CATALYSTS; ROUTES; AL; CO;
D O I
10.1007/s11244-022-01688-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
2,4-Dichlorophenol (2,4-DCP) is a persistent organic compound present in many water reservoirs for human consumption, generating a high risk for all species, especially for humans due to its toxicity. In this work, Mg/Al = 2, 3 and 4 layered double hydroxides activated at 450 degrees C are presented for the formation of photocatalysts formed by the mixture of MgO-MgAl2O4 oxides for the photocatalytic degradation of 2,4-DCP in aqueous solution in a UV irradiated reaction system. The results showed a good photocatalytic activity by achieving a complete degradation of 2,4-DCP up to mineralization. The high degradation capacity of 2,4-DCP is attributed to the presence of holes in these materials that promote the formation of hydroxyl radicals (OH center dot) and superoxide radicals (O-2(center dot-)) in only 30 min of reaction time.
引用
收藏
页码:1469 / 1481
页数:13
相关论文
共 50 条
  • [1] Photocatalytic Degradation of 2,4-Dichlorophenol in Water Using MgAl Activated Hydrotalcites as Photocatalyst
    Esthela Ramos-Ramírez
    Norma Gutiérrez-Ortega
    Francisco Tzompantzi-Morales
    Julio Castillo-Rodríguez
    Arturo Barrera-Rodríguez
    Gloria Del Ángel
    Mirella Gutiérrez-Arzaluz
    Raúl Pérez-Hernández
    María del Pilar Guevara-Hornedo
    Topics in Catalysis, 2022, 65 : 1469 - 1481
  • [2] Sorption of 2,4-dichlorophenol on modified hydrotalcites
    Klumpp, E
    Contreras-Ortega, C
    Klahre, P
    Tino, FJ
    Yapar, S
    Portillo, C
    Stegen, S
    Queirolo, F
    Schwuger, MJ
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 230 (1-3) : 111 - 116
  • [3] Photocatalytic degradation of 2,4-dichlorophenol using nanomaterials silver halide catalysts
    Moja, Mahlako Mary
    Mapossa, Antonio Benjamim
    Chirwa, Evans Martin Nkhalambayausi
    Tichapondwa, Shepherd
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2024, 31 (08) : 11857 - 11872
  • [4] Photocatalytic degradation of 2,4-dichlorophenol using nanomaterials silver halide catalysts
    Mahlako Mary Moja
    António Benjamim Mapossa
    Evans Martin Nkhalambayausi Chirwa
    Shepherd Tichapondwa
    Environmental Science and Pollution Research, 2024, 31 : 11857 - 11872
  • [5] Photocatalytic degradation of 2,4-dichlorophenol using nanoscale Fe/TiO2
    Liu, Lifen
    Chen, Fang
    Yang, Fenglin
    Chen, Yongsheng
    Crittenden, John
    CHEMICAL ENGINEERING JOURNAL, 2012, 181 : 189 - 195
  • [6] Photocatalytic degradation of 2,4-dichlorophenol wastewater using porphyrin/TiO2 complexes activated by visible light
    Chang, Ming-Yi
    Hsieh, Yung-Hsu
    Cheng, Ta-Chih
    Yao, Kuo-Shan
    Wei, Ming-Chi
    Chang, Chen-Yu
    THIN SOLID FILMS, 2009, 517 (14) : 3888 - 3891
  • [7] Degradation of 2,4-dichlorophenol by using glow discharge electrolysis
    Lu, Quanfang
    Yu, He
    Gao, Jinzhang
    JOURNAL OF HAZARDOUS MATERIALS, 2006, 136 (03) : 526 - 531
  • [8] Effects of 2,4-dichlorophenol on activated sludge
    E. Sahinkaya
    F. Dilek
    Applied Microbiology and Biotechnology, 2002, 59 : 361 - 367
  • [9] Effects of 2,4-dichlorophenol on activated sludge
    Sahinkaya, E
    Dilek, FB
    APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2002, 59 (2-3) : 361 - 367
  • [10] DEGRADATION OF 2,4-DICHLOROPHENOL IN METHANOGENIC SYSTEMS
    JAIN, V
    BHATTACHARYA, SK
    UBEROI, V
    ENVIRONMENTAL TECHNOLOGY, 1994, 15 (06) : 577 - 584