Synthesis and characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) molecular precursors to Zr/B/Si/O and Hf/B/Si/O materials

被引：2
作者：
Fujdala, KL
Tilley, TD [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA USA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 13-14期
关键词：
zirconium; hafnium; oxide materials; siloxide; borosiloxide; precursor;
D O I：
10.1002/zaac.200500128
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new transition metal complexes containing the -OB[OSi(O'Bu)(3)](2) ligand, Et2NM{OB[OSi(O'Bu)(3)](2)}(2) (M = Zr, Hf), are reported. These species are the 4(th) and 5(th) examples of complexes containing this recently reported borosiloxide ligand. Their use as potential molecular precursors to multi-component oxide materials via the thermolytic molecular precursor (TMP) method is discussed.
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页码：2619 / 2622
页数：4
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