Synthesis of Elongated Esters from Alkenes

被引：37
作者：
Miura, Tomoya [1 ]
Funakoshi, Yuuta [1 ]
Nakahashi, Junki [1 ]
Moriyama, Daisuke [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 47期
关键词：
alkenes; esters; photocatalysis; radicals; ylides; BOND-DISSOCIATION ENERGIES; TRANSFER RADICAL-ADDITION; CATALYTIC HYDROTRIFLUOROMETHYLATION; PHOTOREDOX CATALYSIS; UNACTIVATED OLEFINS; 1,2-DIFUNCTIONALIZATION; FUNCTIONALIZATION; HETEROCYCLES; ALKYLATION;
D O I：
10.1002/anie.201809115
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A convenient method for synthesizing elongated aliphatic esters from alkenes is reported. An (alkoxycarbonyl)methyl radical species is generated upon visible-light irradiation of an ester-stabilized phosphorus ylide in the presence of a photoredox catalyst. This radical species adds onto the carbon-carbon double bond of an alkene to produce an elongated aliphatic ester.
引用
收藏
页码：15455 / 15459
页数：5
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