Superhydrophobic-Superoleophilic Polythiophene Films with Tunable Wetting and Electrochromism

被引:81
作者
Pernites, Roderick B. [1 ,2 ]
Ponnapati, Ramakrishna R. [1 ,2 ]
Advincula, Rigoberto C. [1 ,2 ]
机构
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
[2] Univ Houston, Dept Chem & Biomol Engn, Houston, TX 77204 USA
关键词
CONDUCTING POLYMERS; FREE-ENERGY; SURFACES; WATER; ELECTRODEPOSITION; WETTABILITY; TRANSITION; DESIGN; ARRAYS;
D O I
10.1002/adma.201100469
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A non-fluorinated polythiophene film with dual superhydrophobic and superoleophilic wetting properties involving 2D assembly of polystyrene (PS) latex particles and electropolymerization is demonstrated. The phenomenon is stable at a wide range of temperatures and pH. It is easily and rapidly reversed with voltage or surfactant coincident with electrochromism.
引用
收藏
页码:3207 / +
页数:8
相关论文
共 36 条
[1]   Purity of the sacred lotus, or escape from contamination in biological surfaces [J].
Barthlott, W ;
Neinhuis, C .
PLANTA, 1997, 202 (01) :1-8
[2]   Self-cleaning surfaces - virtual realities [J].
Blossey, R .
NATURE MATERIALS, 2003, 2 (05) :301-306
[3]   POLARONS, BIPOLARONS, AND SOLITONS IN CONDUCTING POLYMERS [J].
BREDAS, JL ;
STREET, GB .
ACCOUNTS OF CHEMICAL RESEARCH, 1985, 18 (10) :309-315
[4]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[5]   Super water- and highly oil-repellent films made of fluorinated poly(alkylpyrroles) [J].
Chiba, Kaori ;
Kurogi, Kazutomo ;
Monde, Kenji ;
Hashimoto, Mai ;
Yoshida, Masafumi ;
Mayama, Hiroyuki ;
Tsujii, Kaoru .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2010, 354 (1-3) :234-239
[6]   Hydrocarbon versus Fluorocarbon in the Electrodeposition of Superhydrophobic Polymer Films [J].
Darmanin, Thierry ;
de Givenchy, Elisabeth Taffin ;
Amigoni, Sonia ;
Guittard, Frederic .
LANGMUIR, 2010, 26 (22) :17596-17602
[7]   Super oil-repellent surfaces from conductive polymers [J].
Darmanin, Thierry ;
Guittard, Frederic .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (38) :7130-7136
[8]   Molecular Design of Conductive Polymers To Modulate Superoleophobic Properties [J].
Darmanin, Thierry ;
Guittard, Frederic .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7928-7933
[9]   Overoxidized polypyrrole with dopant complementary cavities as a new molecularly imprinted polymer matrix [J].
Deore, B ;
Chen, ZD ;
Nagaoka, T .
ANALYTICAL SCIENCES, 1999, 15 (09) :827-828
[10]   Super-hydrophobic surfaces: From natural to artificial [J].
Feng, L ;
Li, SH ;
Li, YS ;
Li, HJ ;
Zhang, LJ ;
Zhai, J ;
Song, YL ;
Liu, BQ ;
Jiang, L ;
Zhu, DB .
ADVANCED MATERIALS, 2002, 14 (24) :1857-1860