Influence of chemical structure of hard segments on physical properties of polyurethane elastomers: a review

被引：85
作者：
Kojio, Ken [1 ,2 ,3 ]
Nozaki, Shuhei [2 ]
Takahara, Atsushi [1 ,2 ,3 ]
Yamasaki, Satoshi [4 ]
机构：
[1] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[2] Kyushu Univ, Grad Sch Engn, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[3] Kyushu Univ, WPI I2CNER, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[4] Mitsui Chem Inc, 580-32 Nagaura, Sodegaura, Chiba 2990265, Japan
来源：
JOURNAL OF POLYMER RESEARCH | 2020年 / 27卷 / 06期
关键词：
Polyurethane; Diisocyanate; Polymer glycol; Hard segment; Microphase-separated structure; Mechanical property; MICROPHASE-SEPARATED STRUCTURE; ALIPHATIC DIISOCYANATE BEARING; CROSS-LINKED POLYMERS; MECHANICAL-PROPERTIES; PHASE-SEPARATION; SPECTROSCOPIC ANALYSIS; AGGREGATION STRUCTURE; THERMOPLASTIC POLYURETHANES; CRYSTALLIZATION BEHAVIOR; CYCLIC CARBONATE;
D O I：
10.1007/s10965-020-02090-9
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hard segments of polyurethanes (PUs) are generally formed from diisocyanate and diol. Diol can be replaced with triol and thiol. These chemical structures of hard segments strongly affect not only a microphase separated structure but mechanical properties of resultant PUs. In this review, we focus on the relationship between chemical structure like symmetry and bulkiness of diisocyanate and mechanical properties of PU. Then, influence of hard segment content, incorporation of 1,1,1-trimethylol propane with trifunctional groups, and alkyldithiol was reviewed mainly on trans-1,4-bis(isocyanatomethyl) cyclohexane-poly(oxytetramethylene) glycol-based PU.
引用
收藏
页数：13
相关论文
共 111 条
  • [1] Morphological studies of polyurethane based pressure sensitive adhesives by tapping mode atomic force microscopy
    Akram, Nadia
    Zia, Khalid Mahmood
    Saeed, Muhammad
    Mansha, Asim
    Khan, Waheed Gul
    [J]. JOURNAL OF POLYMER RESEARCH, 2018, 25 (09)
  • [2] Self-Healing of Covalently Cross-Linked Polymers by Reshuffling Thiuram Disulfide Moieties in Air under Visible Light
    Amamoto, Yoshifumi
    Otsuka, Hideyuki
    Takahara, Atsushi
    Matyjaszewski, Krzysztof
    [J]. ADVANCED MATERIALS, 2012, 24 (29) : 3975 - 3980
  • [3] Design of Polyurethane Composed of Only Hard Main Chain with Oligo(ethylene glycol) Units as Side Chain Simultaneously Achieved High Biocompatible and Mechanical Properties
    Aoki, Daisuke
    Ajiro, Hiroharu
    [J]. MACROMOLECULES, 2017, 50 (17) : 6529 - 6538
  • [4] BARIKANI M, 1987, CELL POLYM, V6, P41
  • [5] Non-lsocyanate Polyurethane Thermoplastic Elastomer: Amide-Based Chain Extender Yields Enhanced Nanophase Separation and Properties in Polyhydroxyurethane
    Beniah, Goliath
    Fortman, David J.
    Heath, William H.
    Dichtel, William R.
    Torkelson, John M.
    [J]. MACROMOLECULES, 2017, 50 (11) : 4425 - 4434
  • [6] Combined Effects of Carbonate and Soft-Segment Molecular Structures on the Nanophase Separation and Properties of Segmented Polyhydroxyurethane
    Beniah, Goliath
    Chen, Xi
    Uno, Brice E.
    Liu, Kun
    Leitsch, Emily K.
    Jeon, Junho
    Heath, William H.
    Scheidt, Karl A.
    Torkelson, John M.
    [J]. MACROMOLECULES, 2017, 50 (08) : 3193 - 3203
  • [7] STRUCTURE OF THE HARD SEGMENTS IN POLYURETHANE ELASTOMERS
    BLACKWELL, J
    GARDNER, KH
    [J]. POLYMER, 1979, 20 (01) : 13 - 17
  • [8] Blundell DJ, 2004, J MACROMOL SCI PHYS, VB43, P125, DOI [10.1018/MB-120027754, 10.1081/MB-120027754]
  • [9] Real time SAXS/stress-strain studies of thermoplastic polyurethanes at large strains
    Blundell, DJ
    Eeckhaut, G
    Fuller, W
    Mahendrasingam, A
    Martin, C
    [J]. POLYMER, 2002, 43 (19) : 5197 - 5207
  • [10] INVESTIGATION OF 2 CRYSTAL FORMS IN MDI BDO-BASED POLYURETHANES
    BRIBER, RM
    THOMAS, EL
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1983, B22 (04): : 509 - 528
12345678910