In this paper, we consider the following Schrodinger-Poisson equation {-Delta u + u + phi u = u(5) + lambda g(u), in Omega, -Delta phi = u(2), in Omega, u, phi = 0, partial derivative Omega. where Omega is a bounded smooth domain in R-3, lambda > 0 and the nonlinear growth of u(5) reaches the Sobolev critical exponent in three spatial dimensions. With the aid of variational methods and the concentration compactness principle, we prove the problem admits at least two positive solutions and one positive ground state solution.