Crystal structure of chlorido{tris[2-(isopropyl-sulfanyl)phenyl]phosphane-κ4P,S,S′,S"}nickel(II) trifluoromethanesulfonate

被引：0
作者：
Takeda, Nobuhiro [1 ]
Oma, Rin [1 ]
Unno, Masafumi [1 ]
机构：
[1] Gunma Univ, Grad Sch Sci & Technol, 1-5-1 Tenjin Cho, Kiryu, Gunma 3768515, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷
基金：
日本学术振兴会;
关键词：
crystal structure; nickel; five-coordinate; tripodal tetradentate ligand; phosphine; thioether; 10; METAL-COMPLEXES; NICKEL(II); COBALT(II); PHOSPHINE;
D O I：
10.1107/S2056989019002068
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complex cation of the title compound, [NiCl{P(C6H4-2-S-i-Pr)(3)}](CF3SO3), has a slightly distorted trigonal-bipyramidal coordination geometry in which three S atoms are located in the equatorial plane, and one P and one Cl atom in the apical positions. In the cation, there are two intramolecular C-H center dot center dot center dot S hydrogen bonds. In the crystal, there are some intermolecular C-H center dot center dot center dot O and C- H center dot center dot center dot F hydrogen bonds formed between the cation and the anion. The trifluoromethanesulfonate anion and one of the methyl groups are both disordered over two sets of sites with occupancies of 0.629 (17):0.371 (17) and 0.786 (14):0.214 (14), respectively.
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页码：350 / +
页数：13
相关论文
共 13 条
  • [1] [Anonymous], 2013, CRYSTALCLEAR
  • [2] The Cambridge Structural Database
    Groom, Colin R.
    Bruno, Ian J.
    Lightfoot, Matthew P.
    Ward, Suzanna C.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 : 171 - 179
  • [3] CRYSTAL AND MOLECULAR STRUCTURE OF 5-COORDINATE COMPLEX CHLOROTRIS(O-METHYLTHIOPHENYL)PHOSPHINENICKEL(2) PERCHLORATE
    HAUGEN, LP
    EISENBER.R
    [J]. INORGANIC CHEMISTRY, 1969, 8 (05) : 1072 - &
  • [4] Structural diversity in coordination chemistry of tridentate and tetradentate polyphosphines of Group 6 to 10 transition metal complexes
    Hierso, JC
    Amardeil, R
    Bentabet, E
    Broussier, R
    Gautheron, B
    Meunier, P
    Kalck, P
    [J]. COORDINATION CHEMISTRY REVIEWS, 2003, 236 (1-2) : 143 - 206
  • [5] Kabuto C., 2010, NIHON KESSHO GAKKAIS, V51, P218, DOI DOI 10.5940/JCRSJ.51.218
  • [6] Mononuclear Ni(III) complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]0/1- (L = thiolate, selenolate, CH2CN, Cl, PPh3):: Relevance to the nickel site of [NiFe] hydrogenases
    Lee, Chien-Ming
    Chuang, Ya-Lan
    Chiang, Chao-Yi
    Lee, Gene-Hsiang
    Liaw, Wen-Feng
    [J]. INORGANIC CHEMISTRY, 2006, 45 (26) : 10895 - 10904
  • [7] 5-COORDINATION IN IRON(II), COBALT(II) AND NICKEL(II) COMPLEXES
    MORASSI, R
    BERTINI, I
    SACCONI, L
    [J]. COORDINATION CHEMISTRY REVIEWS, 1973, 11 (04) : 343 - 402
  • [8] STEREOCHEMISTRY OF 5-COORDINATE NICKEL(II) AND COBALT(II) COMPLEXES
    ORIOLI, PL
    [J]. COORDINATION CHEMISTRY REVIEWS, 1971, 6 (2-3) : 285 - &
  • [9] Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S2053273314026370, 10.1107/S0108767307043930]
  • [10] Activation of C-S Bond by Group 10 Metal Complexes: Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl Groups with Group 10 Metal Compounds
    Takeda, Nobuhiro
    Tanaka, Yusuke
    Oma, Rin
    Sakakibara, Fumiaki
    Unno, Masafumi
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2016, 89 (08) : 922 - 930
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