Synthesis and Protonation of Molybdenum- and Tungsten-Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

被引：64

作者：

Arashiba, Kazuya ^{[1
]}

Sasaki, Kouitsu ^{[1
]}

Kuriyama, Shogo ^{[1
]}

Miyake, Yoshihiro ^{[1
]}

Nakanishi, Haruyuki ^{[2
]}

Nishibayashi, Yoshiaki ^{[1
]}

机构：

[1] Univ Tokyo, Inst Engn Innovat, Sch Engn, Bunkyo Ku, Yayoi, Tokyo 1138656, Japan

[2] Toyota Motor Co Ltd, Fuel Cell Syst Dev Ctr, Mishu Ku, Susono, Shizuoka 4101193, Japan

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 05期

关键词：

ON-BOUND DINITROGEN; COORDINATED DINITROGEN; CATALYTIC-REDUCTION; MOLECULAR NITROGEN; BOND FORMATION; SIDE-ON; AMMONIA; SILYLATION; N-2; ACTIVATION;

D O I：

10.1021/om300011z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel molybdenum- and tungsten dinitrogen complexes bearing PNP-type pincer ligands are prepared and characterized by X-ray analysis. Reactions of these molybdenum- and tungsten-dinitrogen complexes with an excess amount of sulfuric acid in THF at room temperature afford ammonia and hydrazine in good yields.

引用

页码：2035 / 2041

页数：7

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