Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex

被引：314

作者：

Gründemann, S ^{[1
]}

Kovacevic, A ^{[1
]}

Albrecht, M ^{[1
]}

Faller, JW ^{[1
]}

Crabtree, RH ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b107881j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Pyridylmethylimidazolium salts and IrH5(PPh3)(2) give an [(N-C) IrH2(PPh3)(2)](+) species with the imidazole ring bound in the 'wrong way': at C-5, not at the expected C-2.

引用

页码：2274 / 2275

页数：2

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