One-pot synthesis of meso-microporous ZSM-5 and its excellent performance in VOCs adsorption/desorption

被引:17
作者
Dai, Jiqiang [1 ]
Zhao, Cheng [1 ]
Hu, Xiaomei [1 ]
Chen, Dingsheng [1 ]
Yun, Junge [2 ]
Liu, Chengxian [3 ]
Zhong, Min [1 ]
Huang, Daojian [1 ]
Cen, Chaoping [1 ]
Chen, Zhihang [1 ]
机构
[1] Minist Ecol & Environm, Guangdong Key Lab Water & Air Pollut Control, Guangdong Prov Engn Lab Air Pollut Control, South China Inst Environm Sci, 7th West St, Guangzhou 510655, Peoples R China
[2] Guangxi Univ, Sch Resources Environm & Mat, Nanning, Peoples R China
[3] Guangxi Univ, Sch Chem & Chem Engn, Nanning, Peoples R China
关键词
meso-microporous; ZSM-5; zeolites; adsorption; desorption capacity; diffusion coefficient; MESOPOROUS SILICA MATERIALS; CATALYTIC PERFORMANCE; ZEOLITE CATALYST; POROUS MATERIALS; ADSORPTION; CARBON; DIFFUSION; FABRICATION; DESORPTION; MOLECULES;
D O I
10.1002/jctb.6510
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
BACKGROUND The meso-microporous ZSM-5 is used for treating the complicated industrial organic waste gas, owing to its good hydrophobicity, excellent thermal and hydrothermal stability, and lower mass transfer resistance than conventional ZSM-5, resulting in its great adsorption property for volatile organic compounds (VOCs). In this paper, different types of meso-microporous ZSM-5 (NZ5, MZ5) were prepared using the templates and then characterized by X-ray diffraction, infrared spectroscopy, transmission electron microscopy, thermogravimetric analysis, and so on. The adsorption/desorption performance and diffusion mechanism of VOCs on meso-microporous ZSM-5 were further investigated. RESULTS The meso-microporous ZSM-5 (MZ5), prepared with the cationic surfactant, contained not only large and uniform mesopores but also certain amounts micropores. Moreover, it exhibited excellence adsorption performance for organic molecules due to its relatively reasonable porous structure. The rich porous structure might mean that the cationic surfactant had better effects for producing mesopores in zeolite than the organic additives, such as phenyltriethoxy silane. More importantly, it showed the excellent thermal and hydrothermal stability and great desorption property, which was more than 95% within 20 min at 200 degrees C. Finally, the diffusion mechanism of toluene on the meso-microporous ZSM-5 was investigated, which was suitable for Fick's second law under the low adsorption pressure. CONCLUSION The meso-microporous ZSM-5 (MZ5, NZ5), prepared by hydrothermal synthesis method with the template, exhibited excellent adsorption/desorption performance, thermal and hydrothermal stability and lower mass transfer resistance than the conventional ZSM-5 (CZ5) for handling the VOCs. (c) 2020 Society of Chemical Industry
引用
收藏
页码:78 / 87
页数:10
相关论文
共 53 条
[1]   Guidelines for the use and interpretation of adsorption isotherm models: A review [J].
Al-Ghouti, Mohammad A. ;
Da'ana, Dana A. .
JOURNAL OF HAZARDOUS MATERIALS, 2020, 393
[2]   Permeation of aromatic hydrocarbon vapors through silicalite-zeolite membranes [J].
Baertsch, CD ;
Funke, HH ;
Falconer, JL ;
Noble, RD .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (18) :7676-7679
[3]   Activated carbon fibers for efficient VOC removal from diluted streams: the role of surface functionalities [J].
Baur, Guillaume B. ;
Beswick, Oliver ;
Spring, Jonathan ;
Yuranov, Igor ;
Kiwi-Minsker, Lioubov .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2015, 21 (04) :255-264
[4]   A facile route to synthesize mesoporous ZSM-5 with hexagonal arrays using P123 triblock copolymer [J].
Biriaei, Rouholamin ;
Nohair, Bendaoud ;
Kaliaguine, Serge .
MICROPOROUS AND MESOPOROUS MATERIALS, 2020, 298
[5]   HYDROPHOBIC ZEOLITE ADSORBENT - A PROVEN ADVANCEMENT IN SOLVENT SEPARATION TECHNOLOGY [J].
BLOCKI, SW .
ENVIRONMENTAL PROGRESS, 1993, 12 (03) :226-230
[6]   Recrystallisation of mesoporous SBA-15 into microporous ZSM-5 [J].
Campos, A. A. ;
Dimitrov, L. ;
da Silva, C. R. ;
Wallau, M. ;
Urquieta-Gonzalez, E. A. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 95 (1-3) :92-103
[7]   Overview and Industrial Assessment of Synthesis Strategies towards Zeolites with Mesopores [J].
Chal, Robin ;
Gerardin, Corine ;
Bulut, Metin ;
van Donk, Sander .
CHEMCATCHEM, 2011, 3 (01) :67-81
[8]   CO2 adsorption on LTA zeolites: Effect of mesoporosity [J].
Chen, Chao ;
Ahn, Wha-Seung .
APPLIED SURFACE SCIENCE, 2014, 311 :107-109
[9]   Surface diffusion of adsorbed molecules in porous media: Monolayer, multilayer, and capillary condensation regimes [J].
Choi, JG ;
Do, DD ;
Do, HD .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (19) :4005-4031
[10]   Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity [J].
Choi, Minkee ;
Cho, Hae Sung ;
Srivastava, Rajendra ;
Venkatesan, Chithravel ;
Choi, Dae-Heung ;
Ryoo, Ryong .
NATURE MATERIALS, 2006, 5 (09) :718-723