Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution

被引：452

作者：

Doner, Ali ^{[2
]}

Solmaz, Ramazan ^{[1
]}

Ozcan, Muzaffer ^{[3
]}

Kardas, Gulfeza ^{[2
]}

机构：

[1] Bingol Univ, Sci & Letters Fac, Dept Chem, TR-12000 Bingol, Turkey

[2] Cukurova Univ, Sci & Letters Fac, Dept Chem, TR-01330 Adana, Turkey

[3] Cukurova Univ, Dept Sci & Technol Educ, TR-01330 Adana, Turkey

来源：

CORROSION SCIENCE | 2011年 / 53卷 / 09期

关键词：

Mild steel; EIS; Polarization; Electrochemical calculation; Acid corrosion; LOW-CARBON STEEL; ADSORPTION BEHAVIOR; SCHIFF-BASE; TRIAZOLE DERIVATIVES; ORGANIC-COMPOUNDS; PURE IRON; PART I; 1M HCL; EFFICIENCY; MECHANISM;

D O I：

10.1016/j.corsci.2011.05.027

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The inhibition effects of 2-amino-5-mercapto-1,3,4-thiadiazole (2A5MT) and 2-mercaptothiazoline (2MT) on mild steel corrosion in 1.0 M H2SO4 were studied with potentiodynamic polarization, linear polarization resistance and electrochemical impedance spectroscopy techniques. It was shown that both 2A5MT and 2MT act as good corrosion inhibitors for mild steel protection. The high inhibition efficiencies were attributed to the simple blocking effect by adsorption of inhibitor molecules on the steel surface. The effects of the presence of extra NH2 group and N atom in 2A5MT on the ability to act as corrosion inhibitors were investigated by theoretical calculations. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：2902 / 2913

页数：12

共 79 条

[31] The inhibitive effect of 6-amino-m-cresol and its Schiff base on the corrosion of mild steel in 0.5 M HCl medium [J].

Keles, Huelya ;

Keles, Mustafa ;

Dehri, Ilyas ;

Serindag, Osman .

MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (01) :173-179

[32] Adsorption and inhibitive properties of aminobiphenyl and its Schiff base on mild steel corrosion in 0.5 M HCl medium [J].

Keles, Hueya ;

Keles, Mustafa ;

Dehri, Ilyas ;

Serindag, Osman .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 320 (1-3) :138-145

[33] Corrosion inhibition of iron in 1M HCl by 1-phenyl-5-mercapto-1,2,3,4-tetrazole [J].

Kertit, S ;

Hammouti, B .

APPLIED SURFACE SCIENCE, 1996, 93 (01) :59-66

[34] Corrosion monitoring of mild steel in sulphuric acid solutions in presence of some thiazole derivatives - Molecular dynamics, chemical and electrochemical studies [J].

Khaled, K. F. ;

Amin, Mohammed A. .

CORROSION SCIENCE, 2009, 51 (09) :1964-1975

[35] Study of the mechanism and inhibiting efficiency of 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media [J].

Lagrenée, M ;

Mernari, B ;

Bouanis, M ;

Traisnel, M ;

Bentiss, F .

CORROSION SCIENCE, 2002, 44 (03) :573-588

[36] Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium [J].

Lebrini, M ;

Lagrenée, M ;

Vezin, H ;

Gengembre, L ;

Bentiss, F .

CORROSION SCIENCE, 2005, 47 (02) :485-505

[37] Experimental and theoretical investigation of the adsorption behaviour of new triazole derivatives as inhibitors for mild steel corrosion in acid media [J].

Li, Weihua ;

He, Qiao ;

Pei, Changling ;

Hou, Baorong .

ELECTROCHIMICA ACTA, 2007, 52 (22) :6386-6394

[38] Triazolyl blue tetrazolium bromide as a novel corrosion inhibitor for steel in HCl and H2SO4 solutions [J].

Li, Xianghong ;

Deng, Shuduan ;

Fu, Hui .

CORROSION SCIENCE, 2011, 53 (01) :302-309

[39] INTERFACE AND INTERPHASE CORROSION INHIBITION [J].

LORENZ, WJ ;

MANSFELD, F .

ELECTROCHIMICA ACTA, 1986, 31 (04) :467-476

[40] Inhibitory mechanism of mimosa tannin using molecular modeling and substitutional adsorption isotherms [J].

Martinez, S .

MATERIALS CHEMISTRY AND PHYSICS, 2003, 77 (01) :97-102

← 1 2 3 4 5 6 7 8 →