Judd-Ofelt intensity parameters of trivalent lanthanide ions in a NaPO3-BaF2 based fluorophosphate glass

被引：88
作者：
Van Deun, R
Binnemans, K
Görller-Walrand, C
Adam, JL
机构：
[1] Katholieke Univ Leuven, Dept Chem, Coordinat Chem Div, B-3001 Heverlee, Belgium
[2] Univ Rennes 1, Lab Verres & Ceram, UMR CNRS 6512, F-35042 Rennes, France
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1999年 / 283卷 / 1-2期
关键词：
fluorophosphate glass; Judd-Ofelt; spectroscopic properties; lanthanides;
D O I：
10.1016/S0925-8388(98)00895-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The spectroscopic properties of the trivalent lanthanide ions Pr3+, Nd3+, Sm3+, Eu3+, Tb3+, Dy3+, Ho3+, Er3+ and Tm3+ in the fluorophosphate glass 75NaPO(3)-24BaF(2)-1LnF(3) (where Ln=lanthanide ion) are described. The dipole strengths of the transitions in the absorption spectrum are parameterised in terms of three Omega(lambda) (lambda=2, 4 and 6) Judd-Ofelt intensity parameters. (C) 1999 Elsevier Science S.A. All rights reserved.
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收藏
页码：59 / 65
页数：7
相关论文
共 21 条
[1]   ON THE COLOR OF THE TRIVALENT LANTHANIDE IONS [J].
BINNEMANS, K ;
GORLLERWALRAND, C .
CHEMICAL PHYSICS LETTERS, 1995, 235 (3-4) :163-174
[2]   Spectroscopic properties of trivalent lanthanide ions in fluorophosphate glasses [J].
Binnemans, K ;
Van Deun, R ;
Gorller-Walrand, C ;
Adam, JL .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 238 (1-2) :11-29
[3]   Are the Judd-Ofelt intensity parameters sensitive enough to reflect small compositional changes in lanthanide-doped glasses? [J].
Binnemans, K ;
Gorller-Walrand, C .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (10) :L167-L170
[4]   Optical properties of Nd3+-doped fluorophosphate glasses [J].
Binnemans, K ;
Van Deun, R ;
Gorller-Walrand, C ;
Adam, JL .
JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 275 :455-460
[5]   ELECTRONIC ENERGY LEVELS IN TRIVALENT LANTHANIDE AQUO IONS .I. PR3+ ND3+ PM3+ SM3+ DY3+ HO3+ ER3+ AND TM3+ [J].
CARNALL, WT ;
FIELDS, PR ;
RAJNAK, K .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4424-&
[6]  
CARNALL WT, 1968, J CHEM PHYS, V49, P4443, DOI 10.1063/1.1669894
[7]   ELECTRONIC ENERGY LEVELS OF TRIVALENT LANTHANIDE AQUO IONS .4. EU3+ [J].
CARNALL, WT ;
FIELDS, PR ;
RAJNAK, K .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4450-&
[8]  
CARNALL WT, 1968, J CHEM PHYS, V49, P4447, DOI 10.1063/1.1669895
[9]   SPECTROSCOPY OF PRASEODYMIUM(III) IN ZIRCONIUM FLUORIDE GLASS [J].
EYAL, M ;
GREENBERG, E ;
REISFELD, R ;
SPECTOR, N .
CHEMICAL PHYSICS LETTERS, 1985, 117 (02) :108-114
[10]   Application of standard and modified Judd-Ofelt theories to a praseodymium-doped fluorozirconate glass [J].
Goldner, P ;
Auzel, F .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (10) :7972-7977
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