Artificial host molecules for the sensing of anions

被引：61

作者：

Schmidtchen, FP ^{[1
]}

机构：

[1] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

来源：

ANION SENSING | 2005年 / 255卷

关键词：

anion host; host-guest chemistry; supramolecular association; statistical thermodynamics; binding models;

D O I：

10.1007/b101160

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The foundations of supramolecular complexation of anions by abiotic host compounds are evaluated, with the purpose of determining their qualitative and quantitative preference over competing species. Starting from a critical assessment of binding models, the perspective goal in terms of molecular thermodynamics is defined and discussed. General consequences for the strategic design of artificial anion hosts are delineated and their translation into receptor structures is suggested. The usage of the available fundamental interaction types for anion binding is illustrated with the help of prototypical, yet concrete, receptors of proven utility.

引用

页码：1 / 29

页数：29

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