Beyond Fe-only hydrogenases:: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x=5,6)

被引：155
作者：
Lawrence, JD [1 ]
Li, HX [1 ]
Rauchfuss, TB [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 16期
关键词：
D O I：
10.1039/b104195a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)(2), which in turn react with Li-2[Fe2S2(CO)(6)] to give Fe-2[(SCH2)(2)NR](CO)(6); in the case of R = CH2CH=CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.
引用
收藏
页码：1482 / 1483
页数：2
相关论文
共 50 条
  • [31] Synthesis and spectroscopic characterisation of compounds with formula [{Fe2(SPh)2(CO)5}Ph2P(CH2)nPPh2{Fe(CO)4}] and [{Fe2(SPh)2(CO)5}2Ph2P(CH2)nPPh2] (n=3, 4 and 6)
    Hourihane, R
    Gray, G
    Spalding, T
    Deeney, T
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 642 (1-2) : 40 - 47
  • [32] THE REACTIVITY OF 1-DIETHYLAMINOPROPYNE TOWARDS [FE3(CO)12] AND [FE2(CO)9] - SYNTHESES AND STRUCTURES OF [FE2(CO)6(C50(CH3)2(N(C2H5)2)2)], [FE3(CO)8(C4(CH3)2(N(C2H5)2)2)], [FE2(CO)7(C2(CH3)N(C2H5)2] AND [FE3(CO)8(C4(CH3)2(N(C2H5)2)2)]
    CABRERA, E
    DARAN, JC
    JEANNIN, Y
    KRISTIANSSON, O
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 310 (03) : 367 - 390
  • [33] A Tetranuclear Propane-1,3-Dithiolate Complex, [Fe2(CO)5{Ph2P(CH2)3}{(µ-SCH2)2CH2}]2, with a Bridging 1,6-Bis(diphenylphosphino)hexane Ligand
    Md. Mahfujar Rohman
    Md Imran Hossain
    Nikhil C. Bhoumik
    Shafikul Islam
    Md. Manzurul Karim
    Journal of Chemical Crystallography, 2022, 52 : 223 - 232
  • [34] Synthesis and characterization of starlike complexes containing three terminal butterfly Fe/S cluster cores generated via reactions of the three-μ-CO-containing trianions {[(μ-CO)Fe2(CO)6]3[(μ-SCH2CH2)3N]}3- and {[(μ-CO)Fe2(CO)6]3[1,3,5-(μ-SCH2)3C6H3]}3- with electrophiles
    Song, LC
    Cheng, J
    Gong, FH
    Hu, QM
    Yan, J
    ORGANOMETALLICS, 2005, 24 (15) : 3764 - 3771
  • [35] SYNTHESIS AND STRUCTURE OF CLUSTER MONOMER FE2(CO)6(MU-SCH2CH=CH2)(MU-3-S)FE(CO)2(ETA-5-C5H5)
    KONCHENKO, SN
    MAKSAKOV, VA
    FILIPPOV, IY
    VIROVETS, AV
    PODBEREZSKAYA, NV
    MENDELEEV COMMUNICATIONS, 1992, (04) : 165 - 166
  • [36] MASS-SPECTROMETRY, DTA AND TG METHODS FOR STUDYING IRON CARBONYL CHALCOGENIDES FE2(CO)6X2 (X=S,SE) AND FE3(CO)9X'2 (X'=S,SE,TE)
    CHAUDHURI, MK
    HAAS, A
    ROSENBERG, M
    VELICESCU, M
    WELCMAN, N
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 124 (01) : 37 - 47
  • [37] Influence of Dithiolate Bridges on the Structures and Electrocatalytic Performance of Small Bite-Angle PNP-Chelated Diiron Complexes Fe2(μ-xdt)(CO)4{κ2-(Ph2P)2NR} Related to [FeFe]-Hydrogenases
    Zhao, Pei-Hua
    Hu, Meng-Yuan
    Li, Jian-Rong
    Ma, Zhong-Yi
    Wang, Yan-Zhong
    He, Jiao
    Li, Yu-Long
    Liu, Xu-Feng
    ORGANOMETALLICS, 2019, 38 (02) : 385 - 394
  • [38] Ligand effects on the electrochemical behavior of [Fe2(CO)5(L){μ-(SCH2)2(Ph)P=O}] (L = PPh3, P(OEt)3) hydrogenase model complexes
    Almazahreh, Laith R.
    Imhof, Wolfgang
    Talarmin, Jean
    Schollhammer, Philippe
    Goerls, Helmar
    El-khateeb, Mohammad
    Weigand, Wolfgang
    DALTON TRANSACTIONS, 2015, 44 (16) : 7177 - 7189
  • [39] Electrochemical insights into the mechanisms of proton reduction by [Fe2(CO)6{μ-SCH2N(R)CH2S}] complexes related to the [2Fe]H subsite of [FeFe]hydrogenase
    Capon, Jean-Francois
    Ezzaher, Salah
    Gloaguen, Frederic
    Petillon, Francois Y.
    Schollhammer, Philippe
    Talarmin, Jean
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (06) : 1954 - 1964
  • [40] Reactions Starting from Diiron Propanedithiolate [(μ-SCH2)2CH(OH)]Fe2(CO)6 Leading to Malonyl-, PPh3-, and [60]Fullerene-Containing Compounds Relevant to the Active Site of FeFe-Hydrogenases
    Song, Li-Cheng
    Liu, Xu-Feng
    Ming, Jiang-Bo
    Ge, Jian-Hua
    Xie, Zhao-Jun
    Hu, Qing-Mei
    ORGANOMETALLICS, 2010, 29 (03) : 610 - 617
12345