Beyond Fe-only hydrogenases:: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x=5,6)

被引：155
|
作者：
Lawrence, JD [1 ]
Li, HX [1 ]
Rauchfuss, TB [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 16期
关键词：
D O I：
10.1039/b104195a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)(2), which in turn react with Li-2[Fe2S2(CO)(6)] to give Fe-2[(SCH2)(2)NR](CO)(6); in the case of R = CH2CH=CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.
引用
收藏
页码：1482 / 1483
页数：2
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