Beyond Fe-only hydrogenases:: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x=5,6)

被引：155
|
作者：
Lawrence, JD [1 ]
Li, HX [1 ]
Rauchfuss, TB [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 16期
关键词：
D O I：
10.1039/b104195a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)(2), which in turn react with Li-2[Fe2S2(CO)(6)] to give Fe-2[(SCH2)(2)NR](CO)(6); in the case of R = CH2CH=CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.
引用
收藏
页码：1482 / 1483
页数：2
相关论文
共 50 条
  • [1] Synthesis and crystal structure of a model for the active sites of Fe-only hydrogenases:: [Fe2(SCH2)2N(3-PhCF3)CO)6]2
    Cheng Lan-Xia
    Ma Cheng-Bing
    Hu Ming-Qiang
    Chen Chang-Neng
    Liu Qiu-Tian
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (01) : 113 - 117
  • [2] Synthesis and Crystal Structure of a Model for the Active Sites of Fe-only Hydrogenases:[Fe2(SCH2)2N(3-PhCF3)(CO)6]2
    程岚霞
    马成丙
    胡明强
    陈昌能
    刘秋田
    Chinese Journal of Structural Chemistry, 2007, (01) : 113 - 117
  • [3] The N-acylated derivatives of parent complex [{(μ-SCH2)2NH}Fe2(CO)6] as active site models of Fe-only hydrogenases:: Synthesis, characterization, and related properties
    Song, Li-Cheng
    Wang, Liang-Xing
    Yin, Bang-Shao
    Li, Yu-Long
    Zhang, Xiao-Guang
    Zhang, Yuan-Wei
    Luo, Xiang
    Hu, Qing-Mei
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 2 (02) : 291 - 297
  • [4] Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x]x- as active site models for Fe-only hydrogenases
    Gloaguen, F
    Lawrence, JD
    Schmidt, M
    Wilson, SR
    Rauchfuss, TB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (50) : 12518 - 12527
  • [5] Di-iron aza diphosphido complexes:: Mimics for the active site of Fe-only hydrogenase, and effects of changing the coordinating atoms of the bridging ligand in [Fe2{μ-(ECH2)2NR}(CO)6]
    Das, P
    Capon, JF
    Gloaguen, F
    Pétillon, FY
    Schollhammer, P
    Talarmin, J
    Muir, KW
    INORGANIC CHEMISTRY, 2004, 43 (26) : 8203 - 8205
  • [6] SynthesisandCrystalStructureofaModelfortheActiveSitesofFe-onlyHydrogenases:[Fe2（SCH2）2N（3-PhCF3）(CO)6]2
    程岚霞
    马成丙
    胡明强
    陈昌能
    刘秋田
    结构化学, 2007, (01) : 113 - 117
  • [7] [Fe2(SR)2(μ-CO)(CNMe)6]2+ and analogues: A new class of diiron dithiolates as structural models for the Hoxair state of the Fe-only hydrogenase
    Rauchfuss, T.B. (rauchfuz@uiuc.edu), 1600, American Chemical Society (126):
  • [8] [Fe2(SR)2(μ-CO)(CNMe)6]2+ and analogues:: A new class of diiron dithiolates as structural models for the HoxAir air state of the Fe-only hydrogenase
    Boyke, CA
    Rauchfuss, TB
    Wilson, SR
    Rohmer, MM
    Bénard, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (46) : 15151 - 15160
  • [9] First generation analogues of the binuclear site in the Fe-only hydrogenases:: Fe2(μ-SR)2(CO)4(CN)22-
    Schmidt, M
    Contakes, SM
    Rauchfuss, TB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) : 9736 - 9737
  • [10] CO Substitution Reactions of Diiron Complexes [{(μ-SCH2)2X}Fe2(CO)6] and [{(μ-SeCH2)2X}Fe2(CO)6] (X = O, CH2) with Ph2PCl/Me3NO To Give Ph2PCl-, Ph2PNMe2-, and Ph2PP(=O)Ph2-Substituted Complexes Related to [ FeFe] Hydrogenases
    Song, Li-Cheng
    Cao, Meng
    Du, Zong-Qiang
    Feng, Zhan-Heng
    Ma, Zhen
    Song, Hai-Bin
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (11) : 1886 - 1895
12345