Stacked Platinum Complexes of the Magnus' Salt Type Inside a Coordination Cage

被引：113
作者：
Clever, Guido H. [1 ,2 ]
Kawamura, Wataru
Tashiro, Shohei [2 ]
Shiro, Motoo
Shionoya, Mitsuhiko [2 ]
机构：
[1] Univ Gottingen, Inst Inorgan Chem, D-37077 Gottingen, Germany
[2] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 11期
关键词：
cage compounds; host-guest systems; metal stacking; platinum; supramolecular chemistry; CRYSTAL-STRUCTURES; GREEN SALT; ENCAPSULATION; CHEMISTRY; PALLADIUM(II); DISCRETE; CAPSULES; GUESTS; CHAINS; HOSTS;
D O I：
10.1002/anie.201108197
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Neatly wrapped up: Alternately stacked square-planar platinum(II) complexes inside a dinuclear coordination cage were prepared to give a discrete and soluble Pt 5-array of the Magnus' salt type. Characterization of the complex in solution was complemented by an X-ray crystal structure of {[Pt(pyridine) 4]· [PtCl 4] 2@Cage}; this structure showed the linear, pentanuclear array within the cages and their circular packing into a hollow tubular superstructure. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：2606 / 2609
页数：4
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