Synthesis and photophysical properties of nanocomposites of aluminum tetrasulfonated phthalocyanine covalently linked to glutathione capped CdTe/CdS/ZnS quantum dots

被引：12

作者：

Oluwole, David O. ^{[1
]}

Britton, Jonathan ^{[1
]}

Mashazi, Philani ^{[1
]}

Nyokong, Tebello ^{[1
]}

机构：

[1] Rhodes Univ, Dept Chem, ZA-6140 Grahamstown, South Africa

来源：

SYNTHETIC METALS | 2015年 / 205卷

基金：

新加坡国家研究基金会;

关键词：

Triplet quantum yield; Triplet lifetime; Quantum dots; Aluminium tetrasulfonated phthalocyanine; Core/shell-shell; ENERGY-TRANSFER; HIGHLY LUMINESCENT; ELECTRON-TRANSFER; SINGLET OXYGEN; BEHAVIOR; CELLS; WATER; NANOPARTICLES; GENERATION; MODEL;

D O I：

10.1016/j.synthmet.2015.04.015

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Aluminum tetrasulfonated phthalocyanine (ClAITSPc) was covalently linked with different sizes of glutathione capped CdTe/CdS/ZnS quantum dots (QDs). The photophysical and Forster resonance energy transfer (FRET) properties of the nanoconjugates were investigated. The CdTe/CdS/ZnS(6.3) nanocomposite showed the highest enhancement in its photophysical properties while (CdTe/CdS/ZnS(3.2) nanocomposite showed the least. Highest FRET efficiency was observed in the linked CdTe/CdS/ZnS(6.3) nanocomposites at 93%. Hence, the combination of CdTe/CdS/ZnS with ClAlTSPc exhibited excellent photophysical properties. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：212 / 221

页数：10

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