Ionic mobility, structure, and conductivity of 45ZrF4-35BiF3-20CsF glass according to 19F NMR, IR, Raman, and impedance spectroscopy

被引：1

作者：

Kavun, V. Ya ^{[1
]}

Voit, E. I. ^{[1
]}

Sinebryukhov, S. L. ^{[1
]}

Podgorbunskii, A. B. ^{[1
]}

Brovkina, O. V. ^{[1
]}

Merkulov, E. B. ^{[1
]}

Goncharuk, V. K. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 52卷 / 06期

关键词：

bismuth fluorozirconate glasses; F-19 NMR spectra; ionic mobility; IR; Raman spectroscopy; ionic conductivity; FLUOROZIRCONATE GLASSES; FLUORIDE GLASSES;

D O I：

10.1134/S0022476611060102

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

F-19 NMR, IR, Raman and impedance spectroscopy are used to study the ionic mobility, structure, and conductivity of 45ZrF(4)-35BiF(3)-20CsF bismuth fluorozirconate glass. With the increase in temperature from 150 K to 500 K the fluorine-containing groups pass from the rigid lattice to local movements (reorientations), and then to diffusion. According to the results of IR and Raman spectroscopy, the lattice of this glass consists of ZrF8 polyhedra linked by their vertices into chains. The glass has high ionic conductivity: sigma a parts per thousand 1.8x10(-4) S/cm in a temperature range of 480-485 K.

引用

页码：1102 / 1105

页数：4

共 14 条

[1] Ionic mobility, structure, and conductivity of 45ZrF4-35BiF3-20CsF glass according to 19F NMR, IR, Raman, and impedance spectroscopy
V. Ya. Kavun
E. I. Voit
S. L. Sinebryukhov
A. B. Podgorbunskii
O. V. Brovkina
E. B. Merkulov
V. K. Goncharuk
Journal of Structural Chemistry, 2011, 52 : 1102 - 1105
[2] Ionic mobility and electrical transport in 45ZrF4 · 35BiF3 · 20MF (M - Li, Na, K) glasses studied by NMR and impedance spectroscopy
V. Ya. Kavun
E. B. Merkulov
S. L. Sinebryukhov
S. V. Gnedenkov
V. K. Goncharuk
Inorganic Materials, 2009, 45
[3] Synthesis, Ionic Mobility, and Conductivity of Composites Based on Tin and Lead Difluorides According to the 19F NMR and Impedance Spectroscopy Data
Slobodyuk, A. B.
Telin, I. A.
Polyantsev, M. M.
Uvarov, N. F.
Kavun, V. Ya.
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2024, 60 (06) : 459 - 467
[4] Ionic mobility and electrical transport in 45ZrF4 • 35BiF3 • 20MF (M-Li, Na, K) glasses studied by NMR and impedance spectroscopy
Kavun, V. Ya.
Merkulov, E. B.
Sinebryukhov, S. L.
Gnedenkov, S. V.
Goncharuk, V. K.
INORGANIC MATERIALS, 2009, 45 (03) : 315 - 321
[5] Ionic mobility and structure of glasses in Zrf4-Bif3-Mf2 (M = Sr, Ba, Pb) systems according to Nmr, Ir, and Raman spectroscopic data
Kavun, V. Ya.
Slobodyuk, A. B.
Voit, E. I.
Sinebryukhov, S. L.
Merkulov, E. B.
Goncharuk, V. K.
JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 51 (05) : 862 - 868
[6] Structure and ion mobility in glasses in the BiF3-PbF2-ZrF4 systems studied by Raman and NMR spectroscopy
Kavun, V. Ya
Voit, E. I.
Yaroshenko, R. M.
Goncharuk, V. K.
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2014, 401 : 224 - 231
[7] Ionic mobility and structure of glasses in Zrf4—Bif3—Mf2 (M = Sr, Ba, Pb) systems according to Nmr, Ir, and Raman spectroscopic data
V. Ya. Kavun
A. B. Slobodyuk
E. I. Voit
S. L. Sinebryukhov
E. B. Merkulov
V. K. Goncharuk
Journal of Structural Chemistry, 2010, 51 : 862 - 868
[8] Ionic mobility and structure of glasses based on indium and bismuth fluorides from data of IR and 19F NMR spectroscopy
Kavun, VY
Merkulov, EB
Ignat'eva, LN
Goncharuk, VK
GLASS PHYSICS AND CHEMISTRY, 2000, 26 (02) : 199 - 201
[9] Ionic mobility in glasses in the ZrF4-BiF3-MF systems (M = Li, Na, K) as probed by 7Li, 19F, and 23Na NMR
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia
Russ. J. Inorg. Chem., 2008, 3 (418-424):
[10] Ionic Mobility in Glasses in the ZrF4-BiF3-MF Systems (M = Li, Na, K) as Probed by 7Li, 19F, and 23Na NMR
V. Ya. Kavun
E. B. Merkulov
N. A. Logoveev
A. B. Slobodyuk
V. K. Goncharuk
Russian Journal of Inorganic Chemistry, 2008, 53 : 418 - 424

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