We linearly analyzed the effect of the Prandtl number (Pr) on the stability of thermocapillary flow in shallow annular pools with an aspect ratio Gamma = (R-o - R-i)/d = 20 and two radius ratios Gamma(R) = R-i/R-o= 0.50 and 0.98039, where d, R-o, and R-i are the liquid depth and the radii of the heated outer wall and the cooled inner wall, respectively. The results for Pr is an element of [0, 10(2)] show that the steady axisymmetric thermocapillary flows in these annular pools become unstable against oscillatory instability modes, OSC1, OSC2 and hydrothermal wave (HTW). Two co-dimension-two bifurcations occur at Pr-1* and Pr-2*. The critical mode for Pr <= Pr-1* is OSC2 with almost constant critical Reynolds number Re-c, large wave number and high frequency. OSC1 with smaller wave number and lower frequency is the critical mode for Pr-1* <= Pr <= Pr-2* and Re-c slightly decreases with increasing Pr. HTW is the critical mode for Pr >= Pr-2* and Re c decreases with increasing Pr. The values of (Pr-1*, Pr-2*) are (0.00953, 0.03054) for Gamma(R) = 0.50, and (0.01919, 0.01946) for Gamma(R) = 0.98039. Energy-budget analyses reveal that the instabilities in low-Pr range are caused by instabilities in the steady toroidal vortex (or vortices) near the cold wall. (C) 2019 Elsevier Ltd. All rights reserved.