Decarboxylative oxygenation of carboxylic acids with O2via a non-heme manganese catalyst

被引：22

作者：

Guan, Renpeng ^{[1
]}

Bennett, Elliot L. ^{[1
]}

Huang, Zhiliang ^{[1
]}

Xiao, Jianliang ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

GREEN CHEMISTRY | 2022年 / 24卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

ALPHA-ARYLCARBOXYLIC ACIDS; OXIDATIVE DECARBOXYLATION; AMINO-ACIDS; VIC-DIOLS; DIOXYGEN; COMPLEX; REACTIVITY; PHOTOREDOX; IRON; ACTIVATION;

D O I：

10.1039/d1gc04603a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reported here is a new protocol for the decarboxylative oxygenation of carboxylic acids using a non-heme manganese catalyst under blue light irradiation with O-2 as the sole oxidant. Featuring mild reaction conditions, the protocol allows readily available carboxylic acids to be converted into a wide variety of valuable aldehydes, ketones and amides. Mechanistic studies indicate that the decarboxylation and oxygenation involves the formation of active Mn-oxygen species.

引用

页码：2946 / 2952

页数：7

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