Effect of functionalization of single-wall carbon nanotubes (SWNTs) on the damping characteristics of SWNT-based epoxy composites via multiscale analysis

被引:36
作者
Liu, Ailin [1 ]
Wang, K. W. [1 ]
Bakis, Charles E. [2 ]
机构
[1] Univ Michigan, Dept Mech Engn, Ann Arbor, MI 48109 USA
[2] Penn State Univ, Dept Engn Sci & Mech, University Pk, PA 16802 USA
关键词
Nano-structures; Polymer-matrix composites (PMCs); Internal friction/damping; Multiscale modeling; MECHANICAL-PROPERTIES;
D O I
10.1016/j.compositesa.2011.07.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The influence of carbon nanotube functionalization on damping characteristics of SWNT-based composites is investigated for the first time with a sequential multiscale approach. The process consists of two parts. First, the interfacial shear strength between the functionalized nanotube and the epoxy is calculated by simulating a SWNT pull-out test using the molecular dynamics method. The strength values obtained from atomic simulation are then applied to a micromechanical damping model of a representative unit cell of a SWNT/epoxy composite under cyclic loading. The analysis results indicate that the nanotube functionalization increases the interfacial shear strength. Due to the stick-slip motion at the interfacial surface, the effective loss factor of the epoxy with functionalized nanoropes is sensitive to the applied load/stress. The increased shear strength can either enhance or reduce the damping ability of the composite, depending on the operational load/stress range and nanotube aspect ratio. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1748 / 1755
页数:8
相关论文
共 26 条
[1]  
Allen M. P., 1987, COMPUTER SIMULATION
[2]  
[Anonymous], 2008, DL POLY 2 19
[3]   Measurement of carbon nanotube-polymer interfacial strength [J].
Barber, AH ;
Cohen, SR ;
Wagner, HD .
APPLIED PHYSICS LETTERS, 2003, 82 (23) :4140-4142
[4]   Fracture transitions at a carbon-nanotube/polymer interface [J].
Barber, AH ;
Cohen, SR ;
Eitan, A ;
Schadler, LS ;
Wagner, HD .
ADVANCED MATERIALS, 2006, 18 (01) :83-87
[5]   Measurement of the critical aspect ratio and interfacial shear strength in MWNT/polymer composites [J].
Duncan, Renee K. ;
Chen, Xinyu G. ;
Bult, J. B. ;
Brinson, L. C. ;
Schadler, L. S. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2010, 70 (04) :599-605
[6]  
Frankland S.J.V., 2003, PROC 44 AIAAASME ASC, V2, P1252
[7]   Molecular simulation of the influence of chemical cross-links on the shear strength of carbon nanotube-polymer interfaces [J].
Frankland, SJV ;
Caglar, A ;
Brenner, DW ;
Griebel, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (12) :3046-3048
[8]  
Geng HZ, 2002, ADV MATER, V14, P1387, DOI 10.1002/1521-4095(20021002)14:19<1387::AID-ADMA1387>3.0.CO
[9]  
2-Q
[10]   Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites [J].
Gojny, FH ;
Nastalczyk, J ;
Roslaniec, Z ;
Schulte, K .
CHEMICAL PHYSICS LETTERS, 2003, 370 (5-6) :820-824