Luminescent Photoinduced Electron Transfer (PET) Molecules for Sensing and Logic Operations

被引:75
|
作者
de Silva, A. Prasanna [1 ]
机构
[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland
来源
关键词
FLUORESCENT SENSORS; PH INDICATORS; GATE; COMPUTATION; DERIVATIVES; MICELLES; PLAY;
D O I
10.1021/jz201311p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chemical species can serve as inputs to supramolecular devices so that a luminescence output is created in a conditional manner. Conditionality is built into these devices by employing the classical photochemical process of photoinduced electron transfer (PET) to compete with luminescence emission. The response of these devices in the analogue regime leads to sensors that can operate in nanometric, micrometric, and millimetric spaces. Some of these devices serve in membrane science, cell physiology, and medical diagnostics. The response in the digital regime leads to Boolean logic gates. Some of these find application in improving aspects of medical diagnostics and in identifying small objects in large populations.
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页码:2865 / 2871
页数:7
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