Ferromagnetic coupling through spin polarization in a dinuclear copper(II) metallacyclophane

被引:0
|
作者
Fernández, I
Ruiz, R [1 ]
Faus, J
Julve, M
Lloret, F
Cano, J
Ottenwaelder, X
Journaux, Y
Muñoz, MC
机构
[1] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Valencia, Spain
[2] Univ Valencia, Fac Quim, Inst Ciencia Mol, Dept Quim Inorgan, E-46100 Valencia, Spain
[3] Univ Paris 11, Chim Inorgan Lab, UMR 8613, F-91405 Orsay, France
[4] Univ Politecn Valencia, Dept Fis Aplicada, E-46071 Valencia, Spain
关键词
D O I
10.1002/1521-3773(20010817)40:16<3039::AID-ANIE3039>3.0.CO;2-P
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
First organic radicals, now metal complexes: A successful extension to metal complexes of a well-known organic radical approach to ferro-magnetism is exemplified by the triplet ground-state molecule containing two CuII centers connected by a double m-phenylenediamide skeleton of the cyclophane type shown in the scheme.
引用
收藏
页码:3039 / 3042
页数:4
相关论文
共 50 条
  • [1] Ferromagnetic coupling through spin polarization in a dinuclear copper(n) metallacyclophane
    Fernndez, Isabel
    Ruiz, Rafael
    Faus, Juan
    Julve, Miguel
    Lloret, Francesc
    Cano, Joan
    Ottenwaelder, Xavier
    Journaux, Yves
    Carmen Muoz, M.
    2001, Wiley-VCH Verlag (40)
  • [2] Ferromagnetic Coupling by Spin Polarization in a Trinuclear Copper(II) Metallacyclophane with a Triangular Cage-Like Structure
    Dul, Marie-Claire
    Ottenwaelder, Xavier
    Pardo, Emilio
    Lescouezec, Rodrigue
    Journaux, Yves
    Chamoreau, Lise-Marie
    Ruiz-Garcia, Rafael
    Cano, Joan
    Julve, Miguel
    Lloret, Francesc
    INORGANIC CHEMISTRY, 2009, 48 (12) : 5244 - 5249
  • [3] Structural and magnetic properties of two copper(II) complexes based on dinuclear copper(II) metallacyclophane
    Qu, Xiaoni
    Song, Xueyan
    Li, Wei
    Xu, Yunhe
    Li, Licun
    Liao, Daizheng
    Jiang, Zonghui
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (08) : 1287 - 1292
  • [4] Spin control in ladderlike hexanuclear copper(II) complexes with metallacyclophane cores
    Pardo, E
    Bernot, K
    Julve, M
    Lioret, F
    Cano, J
    Ruiz-García, R
    Delgado, FS
    Ruiz-Pérez, C
    Ottenwaelder, X
    Journaux, Y
    INORGANIC CHEMISTRY, 2004, 43 (09) : 2768 - 2770
  • [5] Insights on spin delocalization and spin polarization mechanisms in crystals of azido copper(II) dinuclear complexes through the electron spin density Source Function
    Gatti, Carlo
    Macetti, Giovanni
    Lo Presti, Leonardo
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2017, 73 : 565 - 583
  • [6] mu-Phenolato-mu-benzoato-bridged Dinuclear Copper(II) Cluster with a Ferromagnetic Coupling
    Mikuriya, Masahiro
    Sato, Yuya
    Yoshioka, Daisuke
    X-RAY STRUCTURE ANALYSIS ONLINE, 2018, 34 : 51 - 53
  • [7] Tuning the Spin Ground State in Heterononanuclear Nickel(II)-Copper(II) Cylinders with a Triangular Metallacyclophane Core
    Dul, Marie-Claire
    Ferrando-Soria, Jesus
    Pardo, Emilio
    Lescouezec, Rodrigue
    Journaux, Yves
    Ruiz-Garcia, Rafael
    Cano, Joan
    Julve, Miguel
    Lloret, Francesc
    Fabelo, Oscar
    Pasan, Jorge
    Ruiz-Perez, Catalina
    INORGANIC CHEMISTRY, 2010, 49 (24) : 11264 - 11266
  • [8] Synthesis, characterization and ferromagnetic spin-coupling between chromium(III) and copper(II) ions in oxamido bridged Cu(II)-Cr(III) dinuclear complexes
    Li, YT
    Yan, CW
    Hu, CX
    POLISH JOURNAL OF CHEMISTRY, 2001, 75 (03) : 329 - 336
  • [9] Hetero triply-bridged dinuclear copper(II) compounds with ferromagnetic coupling: a challenge for current density functionals
    Wannarit, Nanthawat
    Pakawatchai, Chaveng
    Mutikainen, Ilpo
    Costa, Ramon
    Moreira, Iberio de P. R.
    Youngme, Sujittra
    Illas, Francesc
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (06) : 1966 - 1975
  • [10] Ferromagnetic coupling through spin polarization in the hexanuclear [MnII3CUII3] complex
    Pascu, M
    Lloret, F
    Avarvari, N
    Julve, M
    Andruh, M
    INORGANIC CHEMISTRY, 2004, 43 (17) : 5189 - 5191