Thermophysical properties of polypropylene/aluminum composites

被引:87
作者
Boudenne, A
Ibos, L
Fois, M
Gehin, E
Majeste, JC
机构
[1] Univ Paris 12, Ctr Etude & Rech Therm Energet & Syst, F-94010 Creteil, France
[2] Univ Havre, Unite Rech Chim Organ & Macromol, F-76058 Le Havre, France
[3] Univ St Etienne, UMR 5156, Lab Rheol Matieres Plast, F-42023 St Etienne 02, France
关键词
thermal properties; differential scanning calorimetry (DSC); composites; polypropylene (PP);
D O I
10.1002/polb.10713
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This article is dedicated to the study of the thermal parameters of composite materials. A nonlinear least-squares criterion is used on experimental transfer functions to identify the thermal conductivity and the diffusivity of aluminum-polymer composite materials. The density measurements were achieved to deduce the specific heat and thereafter they were compared to values given by differential scanning calorimetry measurement. The thermal parameters of the composite material polypropylene/aluminum were investigated for the two different types of aluminum filler sizes. The experimental data were compared with several theoretical thermal conductivity prediction models. It was found that both the Agari and Bruggeman models provide a good estimation for thermal conductivity. The experimental values of both thermal conductivity and diffusivity have shown a better heat transport for the composite filled with large particles. (C) 2004 Wiley Periodicals, Inc.
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页码:722 / 732
页数:11
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